Disclosed is a flow battery pack with a monitoring system. The flow battery pack with a monitoring system comprises a battery pack device and a monitoring device. The battery pack device comprises a pole plate, and the pole plate is provided thereon with a measuring port. The monitoring device comprises a measuring probe, and the measuring probe extends to the interior of the battery pack device and is arranged corresponding to the measuring port on the pole plate. The monitoring device is used for monitoring the flow pressure and temperature at the measuring port. According to the technical solution of the present disclosure, a monitoring device is introduced into the interior of a flow battery pack, and the real values of correlative parameters of the interior of the battery pack and the distribution status thereof can be obtained through the monitoring device.