Invention Grant
- Patent Title: Controlled radical polymerization, and catalysts useful therein
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Application No.: US14126514Application Date: 2012-06-28
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Publication No.: US09644072B2Publication Date: 2017-05-09
- Inventor: Evgueni E. Nesterov , Jinwoo Choi , Carlos A. Chavez
- Applicant: Evgueni E. Nesterov , Jinwoo Choi , Carlos A. Chavez
- Applicant Address: US LA Baton Rouge
- Assignee: Board of Supervisors of Louisiana State University And Agricultural and Mechanical College
- Current Assignee: Board of Supervisors of Louisiana State University And Agricultural and Mechanical College
- Current Assignee Address: US LA Baton Rouge
- Agent John H. Runnels
- International Application: PCT/US2012/044530 WO 20120628
- International Announcement: WO2013/006357 WO 20130110
- Main IPC: C07C71/00
- IPC: C07C71/00 ; C08G75/06 ; B01J31/24 ; C08F293/00 ; C07F15/04 ; C07F7/18 ; C08G61/12 ; C08L65/00
Abstract:
A catalyst is prepared in situ by reaction between an aryl halide and a Ni(0) complex. The catalyst may be used to promote chain-growth polymerization of halogen-substituted Mg or Zn monomers by a controlled radical mechanism. Polymers, co-polymers, block copolymers, polymer thin films, and surface-confined polymer brushes may be produced using the catalyst.
Public/Granted literature
- US20140114023A1 Controlled Radical Polymerization, and Catalysts Useful Therein Public/Granted day:2014-04-24
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