Electrically conductive synthetic fiber and fibrous substrate (e.g. synthetic leather) are disclosed. The electrically conductive polymeric fiber and polymeric fibrous substrate are made electrically conductive by the use of an electrically conductive polymer disposed on the fibers and in contact with inorganic desiccant particles located at the surface of the fibers. The new material finds utility as an electrode for devices and as a resistive heating element, and as a pathway to efficient thermoelectrics.