To provide a combination of a cylinder made of a hypereutectic Al—Si alloy and a hard-carbon-coated piston ring both exhibiting excellent wear resistance, the piston ring is provided with a laminate coating at least on an outer peripheral sliding surface thereof; the laminate coating comprising a metal layer, a metal-containing, hard carbon layer, and a metal-free, hard carbon layer in this order from the substrate side; the laminate coating having Martens' hardness (indentation hardness) HMs of 5-13 GPa, indentation modulus E of 70-200 GPa, and a deformation ratio Rpe of 0.45 or less, which is expressed by a ratio (Wp/We) of plastic deformation energy Wp to elastic deformation energy We; and a ratio (Tmf/Tm) of the thickness Tmf of the metal-free, hard carbon layer to the thickness Tm of the metal-containing, hard carbon layer being 2-8.