Provided is a fluid control valve assembly including: a main valve body having a first flow passage that is mounted on an inlet of a high-pressure vessel and through which a charging source gas passes, a second flow passage through which a feeding source gas passes, and a third flow passage to which the first flow passage and the second flow passage are connected; a manual valve that is mounted on the main valve body and that opens and closes the third flow passage; a solenoid valve that is mounted on the main valve body and that opens and closes the second flow passage by an electrical signal; a first check valve that is provided on the first flow passage to thus block a reverse flow of the charging source gas; and a second check valve that is provided on the second flow passage to thus block a reverse flow of the feeding source gas, and block the charging source gas from flowing in the second flow passage, to thereby prevent the charging source gas from flowing in the solenoid valve. Accordingly, a charging gas pressure of a high-pressure is prevented from being applied to a solenoid valve, to thereby prevent damage to the solenoid valve and to prevent a malfunction of the solenoid valve.