Invention Grant
- Patent Title: Methods for extracting rare-earth metals and preparing gypsum plaster from phosphogypsum hemihydrate
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Application No.: US14773716Application Date: 2013-11-08
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Publication No.: US09657371B2Publication Date: 2017-05-23
- Inventor: Mikhail Vladimirovich Genkin , Aleksey Vladimirovich Evtushenko , Aleksey Aleksandrovich Komkov , Alfiya Minerovna Safiulina , Vasiliy Sergeevich Spiridonov , Sergey Vladimirovich Shvetsov
- Applicant: OPENED JOINT STOCK COMPANY “UNITED CHEMICAL COMPANY URALCHEM”
- Applicant Address: RU Moscow
- Assignee: OPENED JOINT-STOCK COMPANY “UNITED CHEMICAL COMPANY URALCHEM”
- Current Assignee: OPENED JOINT-STOCK COMPANY “UNITED CHEMICAL COMPANY URALCHEM”
- Current Assignee Address: RU Moscow
- Agency: Baker & Hostetler LLP
- Priority: RU2013109740 20130305
- International Application: PCT/RU2013/000992 WO 20131108
- International Announcement: WO2014/137240 WO 20140912
- Main IPC: C22B59/00
- IPC: C22B59/00 ; C22B3/06 ; C22B3/10

Abstract:
The present invention relates to a method for complex processing of apatite concentrate resulting in producing concentrate of rare earth metals (REM) and plaster from phosphogypsum, a waste of sulphuric acid technology for producing phosphoric acid from apatite. The method comprises leaching of REM into solution by recrystallization of hemihydrate or anhydrite of calcium sulphate into dihydrate of calcium sulphate with a soluble calcium salt at concentrations of 0.075-3.75 M (in terms of Ca2+) and strong acid (pKa0) at a concentration of 0.2-8.0 M (in terms of H+). Recovery of REM into solution is up to 98%, the residual content of impurities of phosphorus, fluorine and alkali metals in dihydrate of calcium sulphate does not exceed 0.3 wt. %, 0.1 wt. %, 0.05 wt. %, respectively.
Public/Granted literature
- US20160047015A1 A method for extracting rare-earth metals Public/Granted day:2016-02-18
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