The present disclosure provides an ink jet print head face plate. The ink jet print head face plate includes a face plate; and a siloxyfluorocarbon networked polymer disposed on the face plate. The siloxyfluorocarbon networked polymer is a polymerization product of a mixture including from about 2 to about 12 alkoxysilane precursor materials, wherein at least one of the alkoxysilane precursor materials is a hydrophobic alkoxysilane precursor material; and at least one of the alkoxysilane precursor materials is an aromatic alkoxysilane precursor material. The siloxyfluorocarbon networked polymer is insoluble in solvents selected from the group consisting of ketones, chlorinated solvents and ethers.