Provided is a multilayered structure comprising at least one fine cellulose fiber nonwoven fabric layer made of a fine cellulose fiber, wherein the multilayered structure is characterized in that the mean fiber diameter of the fine cellulose fiber forming the fine cellulose fiber non-woven fabric layer is 0.005 to 0.5 μm, and the mean thickness of the multilayered structure is 10 to 200 μm, the density thereof is 0.10 to 0.90 g/cm3, and the permeability resistance thereof is 2000 s/100 ml or more. Also provided are an energy recovery ventilation sheet made of this multilayered structure, an energy recovery ventilation element using this energy recovery ventilation sheet as a partitioning material for partitioning two types of air flow of different temperature and/or humidity, and a energy recovery ventilator using this energy recovery ventilation element.