An engine system having a coolant control valve may include a cylinder block configured with cylinders, a cylinder head sitting on top of the cylinder block and comprising exhaust ports and intake ports configured to lead to the cylinders, an Exhaust Gas Recirculation (EGR) cooler, a heater core, an oil cooler, or a radiator through which coolant circulates, and a coolant control valve configured to control a coolant supplied to the cylinder block, a coolant discharged from the cylinder block through the cylinder head, and a coolant supplied to the EGR cooler, the heater core, the oil cooler, or the radiator.