Invention Grant
- Patent Title: Solid polyaluminoxane composition, olefin polymerization catalyst, olefin polymer production method and solid polyaluminoxane composition production method
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Application No.: US14766396Application Date: 2014-02-07
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Publication No.: US09676879B2Publication Date: 2017-06-13
- Inventor: Kou Tsurugi , Shiori Hanada , Atsushi Shibahara , Kazumori Kawamura , Fumiaki Nishino , Yasuyuki Harada , Wataru Yamada , Akiko Matsumoto , Isao Hara , Tatsuya Nakamura , Toshihiro Muroto
- Applicant: Mitsui Chemicals, Inc.
- Applicant Address: JP Tokyo
- Assignee: MITSUI CHEMICALS, INC.
- Current Assignee: MITSUI CHEMICALS, INC.
- Current Assignee Address: JP Tokyo
- Agency: Foley & Lardner LLP
- Priority: JP2013-023266 20130208; JP2013-212878 20131010
- International Application: PCT/JP2014/052856 WO 20140207
- International Announcement: WO2014/123212 WO 20140814
- Main IPC: C08G79/10
- IPC: C08G79/10 ; C08F4/02 ; C08F4/6592 ; C08F10/00 ; C08F110/02 ; C08F4/659

Abstract:
An object of the invention is to provide a solid polyaluminoxane composition suitably used as a cocatalyst and a catalyst carrier in combination with an olefin oligomerization or polymerization catalyst, without the use of solid inorganic carriers such as silica. The solid polyaluminoxane composition of the invention includes a polyalkylaluminoxane and a trialkylaluminum, and has a solubility in n-hexane at 25° C. of less than 0.50 mol % as measured by a specific method (i), a solubility in toluene at 25° C. of less than 1.0 mol % as measured by a specific method (ii), and a 13 mol % or more molar fraction of alkyl groups derived from the trialkylaluminum moieties relative to the total number of moles of alkyl groups derived from the polyalkylaluminoxane moieties and the alkyl groups derived from the trialkylaluminum moieties as measured with respect to tetrahydrofuran-d8 soluble components by a specific method (iii).
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