Invention Grant
- Patent Title: Fluorine-containing oligomer, nano-silica composite particles using the same, and methods for producing both
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Application No.: US14773163Application Date: 2014-03-06
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Publication No.: US09695263B2Publication Date: 2017-07-04
- Inventor: Katsuyuki Sato , Hideo Sawada
- Applicant: UNIMATEC CO., LTD. , HIROSAKI UNIVERSITY
- Applicant Address: JP Toyko JP Aomori
- Assignee: Unimatec Co., Ltd.,Hirosaki University
- Current Assignee: Unimatec Co., Ltd.,Hirosaki University
- Current Assignee Address: JP Toyko JP Aomori
- Agency: Brinks Gilson & Lione
- Priority: JP2013-044078 20130306; JP2013-044080 20130306
- International Application: PCT/JP2014/055820 WO 20140306
- International Announcement: WO2014/136895 WO 20140912
- Main IPC: C08F220/22
- IPC: C08F220/22 ; C08K3/36

Abstract:
Disclosed is a fluorine-containing oligomer comprising a copolymer of a fluoroalkyl alcohol (meth)acrylic acid derivative of the formula: CnF2n+1(CH2)dOCOCR═CH2 [I], wherein R is a hydrogen atom or a methyl group, n is an integer of 1 to 10, and d is an integer of 1 to 6; and a (meth)acrylic acid derivative of the formula: (CH2═CRCO)mR′ [II], wherein R is a hydrogen atom or a methyl group, m is 1, 2, or 3; and when m is 1, R′ is —OH group, NH2 group that is unsubstituted or mono- or di-substituted with an alkyl group having 1 to 6 carbon atoms, or a monovalent group derived from an alkylene glycol or polyalkylene glycol group containing an alkylene group having 2 or 3 carbon atoms; when m is 2 or 3, R′ is a divalent or trivalent organic group derived from a diol or triol. The copolymerization reaction is performed using a hydrocarbon-based peroxide or azo compound polymerization initiator. Also disclosed are nano-silica composite particles formed as a condensate of the fluorine-containing oligomer and an alkoxysilane with nano-silica particles.
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