A method for controlling an energy storage system for connection to a power system, and such an energy storage system are provided. The method makes use of a model based predictive controller to optimize the charging/discharging rates of energy storage elements in a hybrid energy storage system. The method includes determining respective desired charging/discharging rates for the energy storage elements in dependence upon state of charge predictions from respective models of the storage elements, using model predictive control, and adjusting respective charging/discharging rates of the storage elements in accordance with the determined rates. The energy system includes a controller configured to control respective charging/discharging rates of the energy storage elements in accordance with the method.