Solar energy collection and storage systems and processes of using such systems. Non-direct solar energy collection and storage systems can generate electricity from solar radiation using a solar thermoelectric generator and at the same time capture solar thermal energy in a working fluid. The working fluid can then transfer the heat to a thermal storage medium where the heat can be retrieved on demand to generate electricity and heat a fluid. Direct solar energy collection and storage systems can store solar thermal energy in a thermal storage medium directly from solar radiation and the heat from the thermal storage medium can be used on demand to generate electricity and heat a fluid.