Invention Grant
- Patent Title: Processes to improve reactor stability for the preparation of ethylene-based polymers using asymmetrical polyenes
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Application No.: US15101347Application Date: 2014-12-23
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Publication No.: US09751964B2Publication Date: 2017-09-05
- Inventor: Christopher R. Eddy , John O. Osby , Sean W. Ewart , Sarat Munjal , Stefan Hinrichs , Otto J. Berbee
- Applicant: Dow Global Technologies LLC
- Applicant Address: US MI Midland
- Assignee: Dow Global Technologies LLC
- Current Assignee: Dow Global Technologies LLC
- Current Assignee Address: US MI Midland
- International Application: PCT/US2014/072214 WO 20141223
- International Announcement: WO2015/100351 WO 20150702
- Main IPC: C08F2/00
- IPC: C08F2/00 ; C08F20/06 ; C08F210/00 ; C08F210/02

Abstract:
The invention provides a process to form an ethylene-based polymer, said process comprising polymerizing ethylene and at least one asymmetrical polyene, comprising an “alpha, beta unsaturated—carbonyl end” and a “C—C double bond end,” and wherein the polymerization takes place in the presence of at least one free-radical initiator, and wherein the polymerization takes place in a reactor configuration comprising at least two reaction zones, reaction zone I and reaction zone i (i>2), wherein reaction zone I is downstream from reaction zone I; and wherein at least one chain transfer agent (CTA) is added to the polymerization, and wherein the CTA is a saturated hydrocarbon or an unsaturated hydrocarbon.
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