Invention Grant
- Patent Title: Reverse-phase polymerisation process
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Application No.: US14908925Application Date: 2014-07-29
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Publication No.: US09765167B2Publication Date: 2017-09-19
- Inventor: Robert Haschick , Aleksandra Jelicic , John Scott Barratt , Pascal Hesse , Oliver Soetje , Gabriela Eugenia Fonseca Zepeda , Shankara Narayanan Keelapandal Ramamoorthy , Bjoern Langlotz
- Applicant: BASF SE
- Applicant Address: DE Ludwigshafen
- Assignee: BASF SE
- Current Assignee: BASF SE
- Current Assignee Address: DE Ludwigshafen
- Agency: Oblon, McClelland, Maier & Neustadt, L.L.P.
- Priority: EP13178685 20130731
- International Application: PCT/EP2014/066255 WO 20140729
- International Announcement: WO2015/014826 WO 20150205
- Main IPC: C08F2/46
- IPC: C08F2/46 ; C08F2/50 ; C08G61/04 ; C08F220/56 ; C08F2/32 ; B01J19/12 ; B01J19/24 ; C08F220/06 ; C08F220/20 ; C08F226/10 ; C08F220/38

Abstract:
A reverse-phase suspension polymerization process for the manufacture of polymer beads comprising forming aqueous monomer beads comprising an aqueous solution of water-soluble ethylenically unsaturated monomer or monomer blend and polymerizing the monomer or monomer blend to form polymer beads while suspended in a non-aqueous liquid, and recovering polymer beads, in which the process comprises, providing in a vessel (1) a volume (2) of non-aqueous liquid wherein the volume of non-aqueous liquid extends between at least one polymer bead discharge point (3) and at least one monomer feed point (4), feeding the aqueous monomer or monomer blend through orifices (5) into, or onto, the non-aqueous liquid to form aqueous monomer beads, allowing the aqueous monomer beads to flow towards the polymer bead discharge point subjecting the aqueous monomer beads to polymerization conditions to initiate polymerization to form polymerizing beads, wherein the polymerizing beads have formed polymer beads when they reach the polymer bead discharge point, removing a suspension of the polymer beads in non-aqueous liquid from the vessel at the polymer bead discharge point and recovering water soluble or water swellable polymer beads from the suspension. The invention also relates to the apparatus suitable for carrying out a reverse-phase suspension polymerization and polymer beads obtainable by the process or employing the apparatus.
Public/Granted literature
- US20160159955A1 REVERSE-PHASE POLYMERISATION PROCESS Public/Granted day:2016-06-09
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