The various embodiments herein provide a light emitting concrete composition and a method of synthesizing a light emitting concrete structure. The light emitting concrete composition comprises light-emitting pigments. The light emitting pigments include a titanium powder, a sulphide powder and resins, cement, sand, gravel and water. The method of synthesizing a light emitting concrete structure comprises preparing slurry. The slurry is prepared by mixing sand, gravel, cement and water. Further, a light emitting pigment mixture is prepared. The light emitting pigment mixture is prepared by mixing a titanium powder, resins and a sulphide powder. The light-emitting pigment mixture is added to the slurry. The slurry is molded by adding the slurry in molds. The molds are further kept at a temperature of 15-20° C. for at least 12-14 hours. The slurry is cured at a temperature of less than 30° C. for 24 hours.