Invention Grant
- Patent Title: Substituted mononuclear ruthenium complexes for catalysis of synthetic organic reactions
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Application No.: US14771765Application Date: 2014-02-26
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Publication No.: US09782762B2Publication Date: 2017-10-10
- Inventor: Hideo Nagashima , Yusuke Sunada , Hironori Tsutsumi , Toru Hashimoto , Koji Sakuta
- Applicant: KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION , SHIN-ETSU CHEMICAL CO., LTD.
- Applicant Address: JP Fukuoka-Shi JP Tokyo
- Assignee: KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION,SHIN-ETSU CHEMICAL CO., LTD.
- Current Assignee: KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION,SHIN-ETSU CHEMICAL CO., LTD.
- Current Assignee Address: JP Fukuoka-Shi JP Tokyo
- Agency: Birch, Stewart, Kolasch & Birch, LLP
- Priority: JP2013-040906 20130301
- International Application: PCT/JP2014/054715 WO 20140226
- International Announcement: WO2014/133014 WO 20140904
- Main IPC: C22C5/04
- IPC: C22C5/04 ; B01J31/16 ; B01J31/22 ; C07C209/50 ; C07C5/03 ; C07C9/16 ; C07C13/10 ; C07C13/18 ; C07F7/08 ; C07C15/073 ; C07C15/18 ; C07F15/00 ; C07C29/14 ; C07C213/00 ; C07D223/04

Abstract:
Provided is a mononuclear ruthenium complex that comprises a ruthenium-silicon bond that is represented by formula (1) and that exhibits excellent catalyst activity in each of a hydrosilylation reaction, a hydrogenation reaction, and reduction of a carbonyl compound. In formula (1), R1-R6 either independently represent an alkyl group, an aryl group, an aralkyl group or the like that may be substituted with a hydrogen atom or X, or represent a crosslinking substituent in which at least one pair comprising one of R1-R3 and one of R4-R6 is combined. X represents a halogen atom, an organoxy group, or the like. L represents a two-electron ligand other than CO and phosphine. When a plurality of L are present, the plurality of L may be the same as or different from each other. When two L are present, the two L may be bonded to each other. n and m independently represent an integer of 1 to 3 with the stipulation that n+m equals 3 or 4.
Public/Granted literature
- US20160023197A1 MONONUCLEAR RUTHENIUM COMPLEX AND ORGANIC SYNTHESIS REACTION USING SAME Public/Granted day:2016-01-28
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