Invention Grant
- Patent Title: Process for the continuous production of ethylene glycol from carbohydrates
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Application No.: US15189224Application Date: 2016-06-22
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Publication No.: US09783472B2Publication Date: 2017-10-10
- Inventor: David James Schreck , Ray Chrisman , Brooke Albin , Nye Atwood Clinton , Marion McKinley Bradford
- Applicant: Iowa Corn Promotion Board
- Applicant Address: US IA Johnston
- Assignee: Iowa Corn Promotion Board
- Current Assignee: Iowa Corn Promotion Board
- Current Assignee Address: US IA Johnston
- Agency: Davis, Brown, Koehn, Shors & Roberts, P.C.
- Agent Kent A. Herink
- Main IPC: C07C45/00
- IPC: C07C45/00 ; C07C29/00 ; C07C29/141 ; B01J23/889 ; C07C29/145 ; C07C45/67 ; B01J23/30 ; B01J21/02 ; B01J21/06 ; B01J23/89

Abstract:
A continuous process for converting carbohydrates to ethylene and propylene glycol. The carbohydrates are mixed with water and passed through a reactor at a temperature that hydrolyzes the carbohydrate mixture at least partially to monosaccharides. The reactor has a first zone comprising a retro-aldol catalyst and a second zone comprising a reducing catalyst. The aldose is converted in the first zone into glycolaldehyde by the retro-aldol catalyst and the glycolaldehyde, in the presence of hydrogen, is converted to ethylene glycol in the second zone of the reactor. The reaction products are removed from the reactor and the ethylene glycol is recovered. The selectivity to propylene glycol can be enhanced via feeding ketose as the carbohydrate.
Public/Granted literature
- US20160304423A1 PROCESS FOR THE CONTINUOUS PRODUCTION OF ETHYLENE GLYCOL FROM CARBOHYDRATES Public/Granted day:2016-10-20
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