A pixel structure including an active device and a pixel electrode is provided. The pixel electrode is electrically connected to the active device and includes a main trunk portion and branch portions. The main trunk portion includes a first extending part and a second extending part that cross each other. The plurality of branching portions is connected to the main trunk portion, and each branching portions is separated by the main trunk portion. The branching portions include a plurality of first branching part and a plurality of second branching part. The first extending part separates the first and second branching part. An included angle of at least part of the first branching part and the second extending part is α1, an included angle of at least part of the second branching part and the second extending part is α2, and α1 is not equal to α2.