A method of making a monolithic three dimensional NAND string comprising forming a stack of alternating layers of a first material and a second material different from the first material over a substrate, forming an at least one front side opening in the stack and forming at least a portion of a memory film in the at least one front side opening. The method also includes forming a semiconductor channel in the at least one front side opening and doping at least one of the memory film and the semiconductor channel with fluorine in-situ during deposition or by annealing in a fluorine containing atmosphere.