Invention Grant
- Patent Title: Porous electrode substrate, method for manufacturing same, precursor sheet, membrane electrode assembly, and polymer electrolyte fuel cell
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Application No.: US15077613Application Date: 2016-03-22
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Publication No.: US09825304B2Publication Date: 2017-11-21
- Inventor: Hiroto Tatsuno , Kazuhiro Sumioka , Tadao Samejima
- Applicant: MITSUBISHI RAYON CO., LTD.
- Applicant Address: JP Chiyoda-ku
- Assignee: MITSUBISHI CHEMICAL CORPORATION
- Current Assignee: MITSUBISHI CHEMICAL CORPORATION
- Current Assignee Address: JP Chiyoda-ku
- Agency: Oblon, McClelland, Maier & Neustadt, L.L.P.
- Priority: JP2011-015638 20110127; JP2011-015639 20110127; JP2011-066344 20110324
- Main IPC: H01M4/86
- IPC: H01M4/86 ; H01M4/88 ; H01M4/96 ; D21H13/50 ; D21H17/46 ; D21H19/24 ; D21H25/06 ; H01M8/0234 ; H01M8/1018

Abstract:
According to the present invention, a porous electrode substrate with greater sheet strength, lower production cost, and excellent gas permeability and conductivity as well as its manufacturing method are provided. Also provided are a precursor sheet for forming such a substrate, and a membrane electrode assembly and a polymer electrolyte fuel cell containing such a substrate. The method for manufacturing such a porous electrode substrate includes the following steps [1]˜[3]: [1] a step for manufacturing a sheet material in which short carbon fibers (A) are dispersed; [2] a step for manufacturing a precursor sheet by adding a water-soluble phenolic resin and/or water-dispersible phenolic resin to the sheet material; and [3] a step for carbonizing the precursor sheet at a temperature of 1000° C. or higher. The present invention also relates to a porous electrode substrate obtained by such a manufacturing method as well as a precursor sheet to be used for manufacturing the substrate, a membrane electrode assembly and a polymer electrolyte fuel cell.
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