Invention Grant
- Patent Title: Continuous polyamidation process—II
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Application No.: US15037635Application Date: 2014-11-20
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Publication No.: US09834643B2Publication Date: 2017-12-05
- Inventor: Ernest Keith Marchildon , Karen A. Surgenor , Bryan D. Kaushiva
- Applicant: INVISTA NORTH AMERICA S.A R.L.
- Applicant Address: US DE Wilmington
- Assignee: INVISTA NORTH AMERICA S.A R.L.
- Current Assignee: INVISTA NORTH AMERICA S.A R.L.
- Current Assignee Address: US DE Wilmington
- Agent Robert B. Furr, Jr.; Nicholas P. Lanzatella
- Priority: GB1320518.2 20131120
- International Application: PCT/GB2014/053438 WO 20141120
- International Announcement: WO2015/075458 WO 20150528
- Main IPC: C08G69/28
- IPC: C08G69/28 ; B01J14/00 ; B01J10/00 ; B01J19/00 ; B01J19/18 ; B01J19/24 ; B01J4/00

Abstract:
A continuous process for the manufacture of a polyamide, the process comprising the steps of: (i) flowing a stream A comprising a moltendicarboxylic acid, or a molten dicarboxylic acid-rich mixture comprising a dicarboxylic acid and a diamine, through a first stage and at least one more reaction stage of a vertical multistage reactor, wherein the first stage is at the top of the reactor; (ii) counter-currently flowing a stream B comprising a diamine as either a vapor or a diamine-rich liquid through at least one of the stages below the first reaction stage of said vertical multistage reactor; (iii) accumulating a liquid phase material P comprising polyamide at and/or below the final stage of said reactor; wherein said reactor is equipped with internal features suitable for effecting contact between counter-currently flowing streams A and B; and wherein the process further comprises controlling the viscosity of said liquid phase material P by directly controlling the chemical equilibrium of the polyamidation reaction or by controlling stream B so that the amounts of diamine and dicarboxylic acid introduced into the reactor during the process are stoichiometrically imbalanced. The invention further provides a vertical multistage reactor configured to implement said process.
Public/Granted literature
- US20160289384A1 CONTINUOUS POLYAMIDATION PROCESS - II Public/Granted day:2016-10-06
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