The honeycomb structure includes a honeycomb structure body and a pair of electrode members disposed on a side surface of the honeycomb structure body, each of the pair of electrode members is shaped in the form of a band extending in a cell extending direction, and in a cross section perpendicular to the extending direction of cells, one electrode member is disposed on a side opposite to the other electrode member via a center of the honeycomb structure body, one or more slits opened in the side surface are formed in the honeycomb structure body, the honeycomb structure body has a charging material charged into the at least one slit, the charging material contains aggregates and a neck material, and a ratio (α2/α1) of a thermal expansion coefficient α2 of the charging material to a thermal expansion coefficient α1 of the honeycomb structure body is from 0.6 to 1.5.