A method of making products with a functional relief surface (2) with high resolution up to 10 nm, which is copied from a template (1) or carrier of the negative relief of the surface, the so-called master. The template (1) of the relief surface (2) is provided with at least one layer of geopolymer composite, applied in a precursor state (3), in form of a liquid dispersion or grout in plastic or thixotropic condition, whose thickness is the same or greater than the depth of the template relief (1), at temperatures in the interval from the temperature corresponding to properties of the precursor (3) to the temperature corresponding to thermal decomposition of the precursor (3), and after hardening of geopolymer composite the layer or layers is/are separated from the template (1).