- Patent Title: Bimetallic complex comprising cyclopentadienyl and amidine ligands
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Application No.: US14898500Application Date: 2014-06-18
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Publication No.: US09862736B2Publication Date: 2018-01-09
- Inventor: Alexandra Berthoud , Victor Quiroga Norambuena , Gerard Van Doremaele , Martin Alexander Zuideveld , Henricus Johannes Arts , Richard Thomas William Scott
- Applicant: LANXESS Elastomers B.V.
- Applicant Address: NL Geleen
- Assignee: ARLANXEO NETHERLANDS B.V.
- Current Assignee: ARLANXEO NETHERLANDS B.V.
- Current Assignee Address: NL Geleen
- Priority: EP13172492 20130618
- International Application: PCT/EP2014/062783 WO 20140618
- International Announcement: WO2014/202644 WO 20141224
- Main IPC: C07F17/00
- IPC: C07F17/00 ; C08F4/6592 ; C08F210/16 ; C08F210/18 ; C07F7/28 ; C08F4/659 ; C07C257/18 ; C08F210/02

Abstract:
The present invention relates to a new bimetallic complex of the formula (1) wherein: M is a group 4-6 metal R1 means is a substituent comprising a heteroatom of group 15, through which R1 is bonded to the imine carbon atom; R2-R6 are the same or different and each represents a hydrogen atom, an optionally substituted C1-10 alkyl group, an optionally substituted C1-10 alkoxy group, an optionally substituted C6-20 aryl group, an optionally substituted C6-20 aryloxy group, an optionally substituted C7-20 aralkyl group, an optionally substituted C7-20 aralkyloxy group, a silyl group substituted with optionally substituted C1-20 hydrocarbon group(s), a C1-20 hydrocarbon-substituted amino group or the adjacent R2-R6 may be linked to each other to form a ring; R7-R10 are the same or different and each represents a hydrogen atom, a halogen atom, an optionally substituted C1-10 alkyl group, an optionally substituted C1-10 alkoxy group, an optionally substituted C6-20 aryl group, an optionally substituted C6-20 aryloxy group, an optionally substituted C7-20 aralkyl group, an optionally substituted C7-20 aralkyloxy group, a silyl group substituted with optionally substituted C1-20 hydrocarbon group(s), a C1-20 hydrocarbon-substituted amino group or the adjacent R7-R10 may be linked to each other to form a ring; L is an optional neutral Lewis basic ligand, and j is an integer denoting the number of neutral ligands L; and X is an anionic ligand, and r is an integer denoting the number of anionic ligands X and wherein the two cyclopentadienyl-amidinato-metal-containing moieties as in the brackets are the same or different.
Public/Granted literature
- US20160122370A1 BIMETALLIC COMPLEX COMPRISING CYCLOPENTADIENYL AND AMIDINE LIGANDS Public/Granted day:2016-05-05
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