An apparatus and a method for providing a voice communication service using a Long Term Evolution (LTE) network in an electronic device are provided. A method includes providing a first Voice over LTE (VoLTE) service in a first LTE area, handing over to a second LTE area during the first VoLTE service, when the first VoLTE service ends, determining whether the second LTE area provides a VoLTE service, and when the second VoLTE area does not provide the VoLTE service, limiting the VoLTE service of the electronic device.