Selective alkylation method for producing p, p′-di-alkylated diphenylamine antioxidants
Abstract:
Liquid diphenylamine compositions comprising predominately p,p′-di-alkylated diphenylamines and low amounts of mono-alkylated diphenylamines are prepared by adding an olefin to a mixture comprising mono-alkylated diphenylamines, di-alkylated diphenylamines, Lewis acid catalyst and an amount of another olefin sufficient to suppress dealkylation of the alkylated diphenylamines.
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