Invention Grant
- Patent Title: Continuous synthesis method for a modified diene elastomer, facility for implementing same
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Application No.: US14910213Application Date: 2014-07-11
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Publication No.: US09908949B2Publication Date: 2018-03-06
- Inventor: Charlotte Dire , Jean-Marc Marechal , Margarita Dorato , Mathieu Manceau , Nuno Pacheco
- Applicant: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN , MICHELIN RECHERCHE ET TECHNIQUE S.A.
- Applicant Address: FR Clermont-Ferrand CH Granges-Paccot
- Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN,MICHELIN RECHERCHE ET TECHNIQUE S.A.
- Current Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN,MICHELIN RECHERCHE ET TECHNIQUE S.A.
- Current Assignee Address: FR Clermont-Ferrand CH Granges-Paccot
- Agency: Dickinson Wright PLLC
- Priority: FR1357888 20130808
- International Application: PCT/EP2014/064977 WO 20140711
- International Announcement: WO2015/018599 WO 20150212
- Main IPC: C08C19/25
- IPC: C08C19/25 ; C08C19/44 ; C08L15/00 ; B01J19/18 ; B01J19/24 ; C08F236/10

Abstract:
A continuous method for synthesizing a diene elastomer includes modifying the diene elastomer in a functionalizing device by: a kinetic model according to which the ratio of the rate constants is greater than 1, and a flow represented by a residence time distribution in the functionalizing device that is expressed according to equations 1 or 3: (i) in a functionalizing device having at least one tubular continuous reactor or having at least one cascade of at least two stirred reactors, E 1 ( t ) = 1 2 ( P πθ 1 t ) 1 2 e - P ( θ 1 - t ) 2 4 θ 1 t Eq 1 (ii) in a functionalizing device that is a combination of the device (i) and of a device having at least one continuous stirred reactor, having a residence time distribution characterized by the following equation: E 2 ( t ) = e ( - t θ 2 ) θ 2 Eq 2 the device (ii) having a residence time distribution characterized by the equation 3 below, which is the result of the convolution of equations 1 and 2: E 12 ( t ) = ∫ 0 t E 1 ( t - T ) E 2 ( T ) d T E 12 ( t ) = ∫ 0 t 1 2 ( P πθ 1 ( t - T ) ) 1 2 e - P ( θ 1 - ( t - T ) ) 2 4 θ 1 ( t - T ) e ( - T θ 2 ) θ 2 d T Eq 3
Public/Granted literature
- US20160176991A1 CONTINUOUS SYNTHESIS METHOD FOR A MODIFIED DIENE ELASTOMER, FACILITY FOR IMPLENTING SAME Public/Granted day:2016-06-23
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