Invention Grant
- Patent Title: Method for vapor-phase growth of phase-change thin film, and device for vapor-phase growth of phase-change thin film
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Application No.: US15128395Application Date: 2014-03-28
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Publication No.: US09911916B2Publication Date: 2018-03-06
- Inventor: Yoshihisa Fujisaki , Yoshitaka Sasago , Takashi Kobayashi
- Applicant: HITACHI, LTD.
- Applicant Address: JP Tokyo
- Assignee: HITACH, LTD.
- Current Assignee: HITACH, LTD.
- Current Assignee Address: JP Tokyo
- Agency: Miles & Stockbridge P.C.
- International Application: PCT/JP2014/059219 WO 20140328
- International Announcement: WO2015/145746 WO 20151001
- Main IPC: H01L45/00
- IPC: H01L45/00 ; C23C16/22 ; C23C16/448 ; H01L27/24

Abstract:
In order to form a phase change thin film being flat in a nanometer level and having a good coverage, which is essential for realizing a three-dimensional ultra-high integrated phase change memory, an equipment for vapor phase growth of a phase change thin film is provided which form a phase change thin film at low temperature while the film is being kept in a completely amorphous state. A structure is provided in which an ammonia cracker is connected to a reactor of the equipment for vapor phase growth for a nitrogen radical obtained by decomposing ammonia gas. Consequently, low temperature decomposition of metal organic precursor and film formation on a substrate surface are realized. With the use of this equipment, it is possible to realize a completely amorphous film which has a flat surface at a low temperature of 135° C. using an amine complex as a Ge precursor.
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