The disclosed subject matter includes devices and methods relating to anode assemblies and/or X-ray assemblies. In some aspects, a method of forming an X-ray assembly may include providing an anode base formed of a first material and including a first end. The method may include depositing a second material different from the first material over a first surface of the anode base to form a coated portion of the anode base. The coated portion may be configured such that some backscattered electrons do not travel beyond the coated portion.