Invention Grant
- Patent Title: Metal complex, adsorbent, separating material, and 1, 3-butadiene separation method
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Application No.: US14906908Application Date: 2014-07-01
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Publication No.: US09957285B2Publication Date: 2018-05-01
- Inventor: Keisuke Kishida , Yoshihiro Watanabe , Yoshikuni Okumura
- Applicant: SHOWA DENKO K.K.
- Applicant Address: JP Tokyo
- Assignee: SHOWA DENKO K.K.
- Current Assignee: SHOWA DENKO K.K.
- Current Assignee Address: JP Tokyo
- Agency: Sughrue Mion, PLLC
- Priority: JP2013-155591 20130726
- International Application: PCT/JP2014/067518 WO 20140701
- International Announcement: WO2015/012067 WO 20150129
- Main IPC: B01D53/02
- IPC: B01D53/02 ; B01D53/22 ; B01D69/14 ; C07F3/06 ; B01J20/22 ; B01J20/28 ; C07C7/12 ; C07C201/12 ; C07D213/06 ; C07D213/68 ; C07D213/70 ; B01J20/34 ; B01D53/04 ; B01D53/047

Abstract:
A separating material superior to conventional separating materials, and a separation method are provided, with which 1,3-butadiene is selectively separated and recovered from a mixed gas including 1,3-butadiene and C4 hydrocarbons other than 1,3-butadiene. A metal complex, which comprises a dicarboxylic acid compound (I) (see (I) below) represented by general formula (I), an ion of a metal such as beryllium, and a dipyridyl compound (II) represented by general formula (II), namely L-Z-L (II) (see L below), is characterized by including, as the dipyridyl compound (II), at least two different dipyridyl compounds (II). The metal complex is used as a 1,3-butadiene separating material. Formula (I) L is represented by any of the compounds below.
Public/Granted literature
- US20160159823A1 METAL COMPLEX, ADSORBENT, SEPARATING MATERIAL, AND 1, 3-BUTADIENE SEPARATION METHOD Public/Granted day:2016-06-09
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