An apparatus and a method for charging an LPG fuel vehicle are provided to charge a LPG tank with LPG fuel by decreasing part of pressure in the LPG tank when pressure in the LPG tank, which stores the LPG fuel, is greater than charging pressure. That is, pressure in the LPG tank is decreased to be equal to or lower than charging pressure of a charger and the LPG tank with LPG fuel is charged more smoothly from the charger, by capturing part of the LPG fuel in the LPG tank and allowing the LPG fuel to be combusted in the engine when pressure in the LPG tank of the vehicle is greater than LPG charging pressure of the charger.