Invention Grant
- Patent Title: Redox flow battery that uses complexes of cobalt and iron with amino-alcohol ligands in alkaline electrolytes to store electrical energy
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Application No.: US14912561Application Date: 2014-10-07
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Publication No.: US09960445B2Publication Date: 2018-05-01
- Inventor: Allen J. Bard , Netzahualcoyotl Arroyo
- Applicant: Board of Regents, The University of Texas System
- Applicant Address: US TX Austin
- Assignee: Board of Regents, The University of Texas System
- Current Assignee: Board of Regents, The University of Texas System
- Current Assignee Address: US TX Austin
- Agency: Winstead, P.C.
- Agent Robert A. Voigt, Jr.
- International Application: PCT/US2014/059504 WO 20141007
- International Announcement: WO2015/054260 WO 20150416
- Main IPC: H02J7/00
- IPC: H02J7/00 ; H02J7/14 ; H01M8/18 ; H01M4/38 ; H01M4/60 ; H01M8/083 ; H01M8/20 ; H01M8/08 ; H01M6/16

Abstract:
A redox flow battery that uses metal complexes with amino-alcohol ligands as the electroactive species in alkaline electrolytes to store electrical energy. The battery includes a first and a second electrolyte storage unit that each includes a metal complex selected from transition metals with an amino-alcohol ligand as an electroactive species in an alkaline electrolyte. Such solutions in these electrolyte storage units are each prepared by mixing stoichiometric amounts of a metal ion and an amino-alcohol ligand in water to form a metal-ligand mixture followed by adding an amount corresponding to 3-5 moles/liter of an alkaline electrolyte solution to each metal-ligand mixture to form a metal complex with the amino-alcohol ligand in the alkaline electrolyte to be used by a storage unit. As a result, the operational and maintenance costs of the redox flow battery are reduced while reducing the complexity of the manufacturing process.
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