A method is provided for verifying the authenticity of an article which bears a security mark. The method includes irradiating the security mark with a time-varying light source, ascertaining at least one portion of the emissions spectrum of the irradiated security mark with at least one photodetector, determining the photoluminescence lifetime of the security mark by monitoring the time or frequency response of the photodetector, and verifying the authenticity of the article only if the security mark exhibits a photoluminescence which has a lifetime that falls within the range of appropriate values for each portion of the photoluminescence spectrum for which the photoluminescence lifetime of said security mark was ascertained.