Invention Grant
- Patent Title: Mn+-exchanged beta zeolite, gas adsorbent comprising same, method for producing same, and method for removing nitrogen monoxide
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Application No.: US14897946Application Date: 2014-06-13
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Publication No.: US09968909B2Publication Date: 2018-05-15
- Inventor: Shanmugam Palani Elangovan , Masahiro Yamamoto , Toyohiko Hieda
- Applicant: UNIZEO CO., LTD.
- Applicant Address: JP Tokyo
- Assignee: MITSUI MINING & SMELTING CO., LTD.
- Current Assignee: MITSUI MINING & SMELTING CO., LTD.
- Current Assignee Address: JP Tokyo
- Agency: Westerman, Hattori, Daniels & Adrian, LLP
- Priority: JP2013-125699 20130614
- International Application: PCT/JP2014/065804 WO 20140613
- International Announcement: WO2014/200101 WO 20141218
- Main IPC: B01J20/18
- IPC: B01J20/18 ; B01D53/04 ; C01B39/46 ; B01J20/28 ; B01D53/94 ; B01D53/02

Abstract:
Provided are: a Mn+-exchanged beta zeolite which is useful for the catalytic removal of nitrogen monoxide contained in a gas to be purified even when oxygen is contained in the gas at a high concentration or when the gas has a low temperature; and a method for producing the Mn+-exchanged beta zeolite. The Mn+-exchanged beta zeolite according to the present invention has a SiO2/Al2O3 ratio of 7 to 18, and is ion-exchanged by a Mn+ ion (wherein Mn+ represents a n-valent metal cation; n represents a numeral value of 1 to 3; and M represents an element selected from the group consisting of Ni, Co, Cu, Mn, Zn, Sn, Ag, Li, K, Cs, Au, Ca, Mg, Pt, Pd, Rh and Ir). The amount of the Mn+ ion carried on the Mn+-exchanged beta zeolite is preferably from 0.01 to 2.5 mmol/g relative to the amount of the Mn+-exchanged beta zeolite.
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