Invention Grant
- Patent Title: Catalyst composition and a process for making ultra high molecular weight poly (alpha-olefin) drag reducing agents
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Application No.: US15349351Application Date: 2016-11-11
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Publication No.: US09969826B2Publication Date: 2018-05-15
- Inventor: Muhammad Atiqullah , Abdel Salam Al-Sarkhi , Faisal Mohammed Al-Thenayan , Abdullah Raddad Al-Malki , Wei Xu , Anwar Hossaen
- Applicant: Saudi Arabian Oil Company , King Fahd University of Petroleum & Minerals
- Applicant Address: SA Dhahran SA Dhahran
- Assignee: Saudi Arabian Oil Company,King Fahd University of Petroleum & Minerals
- Current Assignee: Saudi Arabian Oil Company,King Fahd University of Petroleum & Minerals
- Current Assignee Address: SA Dhahran SA Dhahran
- Agency: Dinsmore & Shohl LLP
- Main IPC: B01J31/00
- IPC: B01J31/00 ; B01J37/00 ; C08F210/14 ; F17D1/16 ; F17D3/12

Abstract:
A method of producing ultra high molecular weight (UHMW) C4-C30 α-olefin drag reducing agent (DRA). The method includes polymerizing in a reactor a first α-olefin monomer in the presence of catalyst and hydrocarbon solvent to produce the DRA. The catalyst consists essentially of at least one tertiary monophenyl amine having a formula R1R2N-aryl, where R1 and R2 are the same or different, and each is a hydrogen, an alkyl, or a cycloalkyl group, where at least one of R1 and R2 contain at least one carbon atom; at least one titanium halide having a formula TiXm, where m is from 2.5 to 4.0 and X is a halogen containing moiety; and at least one cocatalyst having a formula AlRnY3-n where R is a hydrocarbon radical, Y is a halogen or hydrogen, and n is 1-20. Further, the catalyst is absent of a carrier or support.
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