Invention Grant
- Patent Title: Method for producing optically active, racemic menthol
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Application No.: US13658003Application Date: 2012-10-23
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Publication No.: US09988331B2Publication Date: 2018-06-05
- Inventor: Gunnar Heydrich , Gabriele Gralla , Matthias Rauls , Joachim Schmidt-Leithoff , Klaus Ebel , Wolfgang Krause , Steffen Oehlenschläger , Christoph Jäkel , Marko Friedrich , Eike Johannes Bergner , Nawid Kashani-Shirazi , Rocco Paciello
- Applicant: BASF SE
- Applicant Address: DE
- Assignee: BASF SE
- Current Assignee: BASF SE
- Current Assignee Address: DE
- Agency: Drinker Biddle & Reath LLP
- Priority: EP07122036 20071130
- Main IPC: C07C29/56
- IPC: C07C29/56 ; C07C29/17 ; C07C29/78 ; C07C45/62 ; C07C45/82

Abstract:
The present invention relates to a particularly economic overall method for producing menthol, specifically for producing optically active, essentially enantiomerically and diastereomerically pure L-menthol and racemic menthol, starting from the starting material citral which is available inexpensively on an industrial scale. The method has the following steps a.1) catalytic hydrogenation of neral and/or geranial to give citronellal, b.1) cyclization of citronellal to isopulegol in the presence of an acidic catalyst, c.1) purification of isopulegol by crystallization and d.1) catalytic hydrogenation of isopulegol to give menthol.
Public/Granted literature
- US20130046118A1 METHOD FOR PRODUCING OPTICALLY ACTIVE, RACEMIC MENTHOL Public/Granted day:2013-02-21
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