Abstract:
A negative electrode composition includes a silicon containing material and a crosslinked polymer containing coating surrounding at least a portion of the silicon containing material. The crosslinked polymer containing coating comprises a (co)polymer derived from polymerization of one or more vinylic monomers comprising a carboxyl or carboxylate group.
Abstract:
An electrode composition is disclosed that includes a silicon alloy containing silicon, iron and optionally carbon. The silicon alloy is capable of undergoing lithiation and delithiation. The electrode composition also includes graphitic carbon, a binder, and a conductive additive containing carbon nanotubes. Such an electrode composition may be used in a negative electrode for an electrochemical cell that also contains a positive electrode and an electrolyte. Also disclosed are batteries containing such electrochemical cells and methods of making electrochemical cells using the electrode composition.