公开(公告)号：US20250011483A1

公开(公告)日：2025-01-09

申请号：US18702151

申请日：2022-10-10

Applicant: Basell Polyolefine GMBH ,  Albert-Ludwigs-Universität Freiburg

Inventor： Carl Gunther Schirmeister ,  Erik Hans Licht ,  Timo Hees ,  Jürgen Rohrmann ,  Rainer Köhler ,  Shahram Mihan ,  Yannic Kessler ,  Rolf Muelhaupt

IPC: C08F210/16 ,  B33Y80/00 ,  C08J5/04

Abstract: A polyolefin composition (I) made from or containing: (A) 15-80% by weight of a heterophasic polymer composition made from or containing: (a) 50-80% by weight of a propylene polymer, and (b) 20-50% by weight of a copolymer of ethylene and an alpha-olefin; and (B) 20-85% by weight of a polyethylene composition made from or containing: (i) 25-85% by weight of a polyethylene component, having a weight average molecular weight Mw(i), equal to or higher than 1,000,000 g/mol; and (ii) 10-65% by weight of a polyethylene component, having an Mw(ii) equal to or lower than 5,000 g/mol, wherein the polyethylene composition (B) is made from or containing at least 70% by weight of (i)+(ii).

公开(公告)号：US09671047B2

公开(公告)日：2017-06-06

申请号：US15028690

申请日：2014-09-24

Applicant: Basell Polyolefine GmbH

Inventor： Heinz Vogt ,  Shahram Mihan ,  Gerd Mannebach ,  Lenka Richter-Lukesova ,  Markus Meierhöfer ,  Holger Brüning

IPC: F16L9/12 ,  C08F10/02 ,  C08F210/16

CPC classification number: F16L9/12 ,  C08F10/02 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/17

Abstract: The present disclosure relates to a polyethylene composition of Raised Temperature Resistance, having the following features: 1) a density from 0.935 to 0.945 g/cm3; 2) a melt flow index MIF from 10 to 18 g/10 min; 3) a melt flow index MIP from 1 to 2.5 g/10 min; and 4) a MIF/MIP ratio from 5 to 10.

公开(公告)号：US20140316082A1

公开(公告)日：2014-10-23

申请号：US14364977

申请日：2012-12-04

Applicant: Basell Polyolefine GmbH

Inventor： Lars Kolling ,  Shahram Mihan

IPC: C08F110/02

CPC classification number: C08F110/02 ,  C08F2/14 ,  C08F10/02 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/07 ,  C08F2500/12 ,  C08F2500/24 ,  C08F4/24

Abstract: The instant invention pertains to a process for preparing an ethylene homo- or copolymer in the presence of a supported chromium catalyst by slurry loop polymerization or copolymerization, whereby the resulting polymer powder has an increased powder density, in which the supported chromium catalyst has a chromium content of from 0.01 to 5 wt.-%, based on the element in the finished catalyst, and shows a particle size distribution measured according to ISO 13320-2009 comprising two main fractions one of which having a d50 of from 15 to 40 μm and the other having a d50 of from 45 to 80 μm said catalyst being further characterized by the fact that less than 10% wt of its catalyst particles has diameter lower than 20 μm.

Abstract translation: 本发明涉及在负载型铬催化剂存在下通过淤浆环聚合或共聚合制备乙烯均聚物或共聚物的方法，由此得到的聚合物粉末具有增加的粉末密度，其中负载的铬催化剂具有铬 基于成品催化剂中的元素含量为0.01至5重量％，并且显示根据ISO 13320-2009测量的粒度分布，其包含两个主要部分，其中一个具有15至40μm的d 50，以及 另一个具有45至80μm的d 50，所述催化剂的特征还在于其小于10重量％的催化剂颗粒的直径小于20μm的事实。

公开(公告)号：US12257767B2

公开(公告)日：2025-03-25

申请号：US17766442

申请日：2020-09-28

Applicant: Basell Polyolefine GmbH ,  Albert-Ludwigs-Universität Freiburg

Inventor： Carl Schirmeister ,  Karsten Schmitz ,  Yannic Kessler ,  Rainer Köhler ,  Erik Licht ,  Shahram Mihan ,  Jürgen Rohrmann ,  Dieter Langenfelder ,  Rolf Muelhaupt ,  Timo Hees

IPC: B29C64/118 ,  B29K23/00 ,  B29K25/00 ,  B33Y10/00 ,  B33Y70/00 ,  B33Y80/00 ,  C08K7/14 ,  C08L23/0807 ,  C08L23/12 ,  C08L23/16 ,  C08L25/08 ,  C08L51/06 ,  C08L53/00

Abstract: A process for producing articles with an extrusion-based additive manufacturing system using a consumable filament made from or containing a propylene polymer composition made from or containing: A) from 20% to 60% by weight of a heterophasic propylene copolymer; B) from 5% to 33% by weight of a propylene homopolymer or copolymer, wherein the copolymer contains up to 5% by weight of an alpha olefin; C) from 2% to 15% by weight of an elastomeric block copolymer made from or containing styrene; D) from 4% to 32% by weight of an elastomeric ethylene copolymer; E) from 5% to 50% by weight of a glass material as filler; and F) from 0.1% to 5% by weight of compatibilizer.

公开(公告)号：US10208144B2

公开(公告)日：2019-02-19

申请号：US15677814

申请日：2017-08-15

Applicant: Basell Polyolefine GmbH

Inventor： Shahram Mihan ,  Gerhardus Meier ,  Ulf Schueller ,  Michael Schiendorfer ,  Jens Wiesecke

IPC: C08F2/00 ,  C08F10/00 ,  C08F110/02 ,  C08F10/02 ,  H01B1/12

Abstract: A process for the preparation of polyolefins by polymerizing olefins at temperatures of from 20 to 200° C. and pressures of from 0.1 to 20 MPa in the presence of a polymerization catalyst and an antistatically acting composition in a polymerization reactor, wherein the antistatically acting composition is a mixture comprising an oil-soluble surfactant and water and the use of an antistatically acting composition comprising an oil-soluble surfactant and water as antistatic agent for the polymerization of olefins at temperatures of from 20 to 200° C. and pressures of from 0.1 to 20 MPa in the presence of a polymerization catalyst.

公开(公告)号：US20150166778A1

公开(公告)日：2015-06-18

申请号：US14407204

申请日：2013-06-19

Applicant: Basell Polyolefine GmbH

Inventor： Fabiana Fantinel ,  Bodo Richter ,  Shahram Mihan ,  Massimo Covezzi ,  Claudio Cavalieri ,  Michele Grazzi

IPC: C08L23/12 ,  C08J5/18

CPC classification number: C08L23/12 ,  C08F4/61912 ,  C08F4/61916 ,  C08F4/65927 ,  C08F4/7042 ,  C08J5/18 ,  C08J2323/16 ,  C08J2423/06 ,  C08J2423/12 ,  C08L23/0815 ,  C08L23/10 ,  C08L23/16 ,  C08L2205/02 ,  C08L2205/03 ,  C08L2314/06 ,  C08L2314/08 ,  Y10T428/139 ,  C08F210/16 ,  C08F2/001 ,  C08F4/61904 ,  C08L23/08 ,  C08L23/142 ,  C08F210/06 ,  C08F2500/04 ,  C08F2500/12 ,  C08F2500/17 ,  C08F2500/21 ,  C08L23/06

Abstract: A two steps polymerization process for obtaining a polyolefin composition comprising: a) from 25 wt % to 70 wt % of a propylene homopolymer or a propylene-ethylene copolymer containing from 0.1 wt % to 10 wt % of ethylene derived units; b) from 27 wt % to 70 wt % of a copolymer of ethylene and at least one C3-C20 alpha olefins, wherein the ethylene derived units content ranges from 15 wt % to 70 wt %; c) from 3 wt % to 20 wt % of polyethylene homopolymer or an ethylene and at least one C3-C20 alpha olefins copolymer; the sum a)+b)+c) being 100, wherein said process comprises: step a) contacting under polymerization conditions propylene, optionally ethylene and the catalyst system in order to obtain component a), step b) contacting under polymerization conditions ethylene and at least one C3-C20 alpha-olefins and the catalyst system in order to obtain components b) and c); wherein the catalyst system comprises a metallocene compound and an iron complex.

Abstract translation: 一种用于获得聚烯烃组合物的两步聚合方法，包括：a）25重量％至70重量％的丙烯均聚物或含有0.1重量％至10重量％乙烯衍生单元的丙烯 - 乙烯共聚物; b）27重量％至70重量％的乙烯和至少一种C 3 -C 20α-烯烃的共聚物，其中乙烯衍生单元含量为15重量％至70重量％; c）3重量％至20重量％的聚乙烯均聚物或乙烯和至少一种C 3 -C 20α-烯烃共聚物; 总和a）+ b）+ c）为100，其中所述方法包括：步骤a）在聚合条件下丙烯，任选的乙烯和催化剂体系接触以获得组分a），步骤b）在聚合条件下使乙烯和 至少一种C 3 -C 20α-烯烃和催化剂体系以获得组分b）和c）; 其中所述催化剂体系包含茂金属化合物和铁络合物。

公开(公告)号：US10202472B1

公开(公告)日：2019-02-12

申请号：US16079229

申请日：2017-02-23

Applicant: Basell Polyolefine GmbH

Inventor： Gerhardus Meier ,  Ulf Schueller ,  Claudio Fibla ,  Shahram Mihan

IPC: C08F10/02 ,  C08F210/16 ,  C08F4/22 ,  C08F2/34 ,  C08F2/38 ,  C08F2/44 ,  C08F2/02

Abstract: A process for the preparation of an ethylene polymer including the step of polymerizing ethylene or copolymerizing ethylene and one or more other olefins in the presence of a Phillips-type chromium catalyst in a gas-phase polymerization reactor containing a reactor bed of particulate polymer, wherein the gas-phase polymerization reactor is equipped with a cycle gas line, wherein the reactor gas returned to the polymerization reactor through the cycle gas line has been condensed in part and the amount of liquid in the returned reactor gas is from 0.5 wt. % to 10 wt. % based upon the total weight of the reactor gas/liquid composition, the polymerization is carried out at from 108° C. to 125° C., and an aluminum alkyl is fed into the polymerization reactor in an amount in the range of from 0.0025 mole to 0.1 mole per ton of dosed ethylene.

公开(公告)号：US09932465B1

公开(公告)日：2018-04-03

申请号：US15560424

申请日：2016-03-23

Applicant: Basell Polyolefine GmbH

Inventor： Gerd Mannebach ,  Bernd Lothar Marczinke ,  Gerhardus Meier ,  Ulf Schueller ,  Shahram Mihan ,  Andreas Maus ,  Pietro Baita ,  Maria Di Diego ,  Lorella Marturano

IPC: C08F2/44 ,  C08F2/38 ,  C08F10/02 ,  C08F210/16 ,  C08L23/06 ,  C08L71/02 ,  C08K5/00 ,  C08F2/34 ,  B01J8/24 ,  B01J8/22

CPC classification number: C08L23/06 ,  B01J8/224 ,  B01J8/24 ,  C08F2/34 ,  C08F2/44 ,  C08F10/00 ,  C08F10/02 ,  C08F210/16 ,  C08F2500/04 ,  C08F2500/07 ,  C08F2500/12 ,  C08K5/0075 ,  C08L71/02 ,  C08F2/005 ,  C08F110/02 ,  C08F2/001

Abstract: A process for preparing a polyolefin, including polymerizing olefins in the presence of an antistatic agent made from or containing an alkylene oxide derived polymer made from or containing in average from about 10 to about 200 repeating units —(CH2—CHR—O)— with R being hydrogen or an alkyl group having from 1 to 6 carbon atoms, wherein the alkylene oxide derived polymer is a random copolymer of ethylene oxide and other alkylene oxides and a ratio of n:m is in the range of from 6:1 to 1:1, wherein (n) is the average number of repeating units —(CH2—CH2—O)— derived from ethylene oxide and (m) is the average number of repeating units —(CH2—CHR′—O)— derived from the other alkylene oxides with R′ being an alkyl group having from 1 to 6 carbon atoms, and the end groups of the alkylene oxide derived polymer are —OH groups.

公开(公告)号：US20160298795A1

公开(公告)日：2016-10-13

申请号：US15028690

申请日：2014-09-24

Applicant: BASELL POLYOLEFINE GMBH

Inventor： Heinz Vogt ,  Shahram Mihan ,  Gerd Mannebach ,  Lenka Richter-Lukesova ,  Markus Meierhõfer ,  Holger Brüning

IPC: F16L9/12 ,  C08F210/16

CPC classification number: F16L9/12 ,  C08F10/02 ,  C08F210/16 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/17

Abstract: The present disclosure relates to a polyethylene composition of Raised Temperature Resistance, having the following features: 1) a density from 0.935 to 0.945 g/cm3; 2) a melt flow index MIF from 10 to 18 g/10 min; 3) a melt flow index MIP from 1 to 2.5 g/10 min; and 4) a MIF/MIP ratio from 5 to 10.

公开(公告)号：US09422319B2

公开(公告)日：2016-08-23

申请号：US14677641

申请日：2015-04-02

Applicant: Basell Polyolefine GmbH

Inventor： Michael W. Lynch ,  Sandor Nagy ,  Shahram Mihan ,  Ilya E. Nifant'ev ,  Pavel V. Ivchenko ,  Vladimir V. Bagrov ,  Igor A. Kashulin

IPC: C08F4/6592 ,  C08F4/653 ,  C08F4/642 ,  C08F4/643 ,  C08F10/00 ,  C07F17/00 ,  C08F4/659

CPC classification number: C07F17/00 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/00 ,  C08F210/16 ,  C08F210/08 ,  C08F2500/01 ,  C08F2500/05 ,  C08F2500/09

Abstract: The present disclosure provides metallocene catalysts for use in polymerization processes. Such catalysts may be used to generate polymers with low branching and high molecular weights. Also, the present disclosure provides methods of bimodal polymerization resulting in a duality of average molecular weight polymers being simultaneously produced. In the system, the size of the polymers produced can be controlled by modifying the type and amount of catalyst activator.

Abstract translation: 本公开提供用于聚合方法的茂金属催化剂。 这种催化剂可用于产生具有低支化和高分子量的聚合物。 此外，本公开提供了双峰聚合的方法，导致同时产生平均分子量聚合物的二元性。 在该系统中，可以通过改变催化剂活化剂的类型和量来控制生产的聚合物的尺寸。