公开(公告)号：CA1248515A

公开(公告)日：1989-01-10

申请号：CA472927

申请日：1985-01-25

Applicant: BASF AG

Inventor： FRANK GERHARD ,  NEUBAUER GERALD

IPC: B01J23/74 ,  B01J23/745 ,  B01J33/00 ,  B01J37/00 ,  B01J37/14 ,  B01J37/18 ,  C07B61/00 ,  C07C67/00 ,  C07C209/00 ,  C07C209/48 ,  C07C211/02 ,  C07C85/12

Abstract: A molded iron catalyst material is useful for the hydrogenation of nitriles to amines owing to its indentation hardness of from 850 to 1500 kp/cm2. The material contains metallic iron particles, obtained from iron oxide particles by contact with hydrogen at less than 500.degree.C, and a lubricant. Its preparation involves reduction, passivation and pressing of the iron particles followed by activation of the resulting moldings.

公开(公告)号：CA1204723A

公开(公告)日：1986-05-20

申请号：CA435169

申请日：1983-08-23

Applicant: BASF AG

Inventor： FRANK GERHARD ,  RUDOLF PETER ,  NEUBAUER GERALD ,  OHLINGER MANFRED ,  WILFINGER HANS J ,  PFANNEBECKER EMIL ,  DUFFNER PAUL

IPC: B01J23/74

Abstract: Molded iron catalysts which contain metallic iron particles, obtained from anisometric iron oxide particles by contact with hydrogen at ? 500.degree.C, and a lubricant, are prepared.

公开(公告)号：FR1484993A

公开(公告)日：1967-06-16

申请号：FR67203

申请日：1966-06-28

Applicant: BASF AG

Inventor： PLATZ ROLF ,  NOHE HEINZ ,  FRANK GERHARD

IPC: C07C5/48 ,  C07C17/00

公开(公告)号：CA1243011A

公开(公告)日：1988-10-11

申请号：CA472928

申请日：1985-01-25

Applicant: BASF AG

Inventor： FRANK GERHARD ,  NEUBAUER GERALD ,  DUFFNER PAUL ,  WILFINGER HANS J

IPC: B01J27/18 ,  B01J23/16 ,  B01J23/70 ,  B01J23/74 ,  B01J23/75 ,  B01J23/755 ,  B01J23/78 ,  B01J23/84 ,  B01J23/889 ,  B01J27/185 ,  B01J33/00 ,  B01J37/00 ,  B01J37/03 ,  C07B61/00 ,  C07C67/00 ,  C07C209/00 ,  C07C209/48 ,  C07C211/02

Abstract: Molded catalyst materials contain metallic cobalt and/or nickel particles and a lubricant, the said particles being obtained by reduction of cobalt oxide and/or nickel oxide particles containing less than 0.1% by weight of alkali metal oxides and/or alkaline earth metal oxides at ? 500.degree.C, and the molded catalyst material having an in entation hardness greater than 300 kp/cm2.

公开(公告)号：CA1231976A

公开(公告)日：1988-01-26

申请号：CA472926

申请日：1985-01-25

Applicant: BASF AG

Inventor： FRANK GERHARD ,  NEUBAUER GERALD ,  DUFFNER PAUL ,  WILFINGER HANS J

IPC: C07B61/00 ,  B01J23/00 ,  B01J23/74 ,  B01J23/84 ,  B01J23/86 ,  B01J23/889 ,  C07C67/00 ,  C07C209/00 ,  C07C209/48 ,  C07C85/12 ,  C07C87/14

Abstract: - 13 - O.Z.0050/36947 Saturated primary amines are prepared by reacting a nitrile with hydrogen at elevated temperatures and under superatmospheric pressure in the presence of ammonia by a process in which a molded catalyst material as used which has an indentation hardness of >300 kp/cm2 and contains metallic cobalt and/or nickel particles, obtained from cobalt oxide and/or nickel oxide particles containing less than 0.1% by weight of alkali metal oxides and/or alkaline earth metal oxides by reduction with hydrogen at

公开(公告)号：CA1220474A

公开(公告)日：1987-04-14

申请号：CA460853

申请日：1984-08-13

Applicant: BASF AG

Inventor： FRANK GERHARD ,  NEUBAUER GERALD

IPC: C07D295/02 ,  B01J23/74 ,  B01J23/745 ,  C07B61/00 ,  C07D207/06 ,  C07D211/02 ,  C07D211/12 ,  C07D223/04 ,  C07D295/023

Abstract: - 10 - O.Z. 0050/36690 5-Membered, 6-membered or 7-membered cyclic imines are prepared by hydrogenating a C2-C4-alkanedinitrile in the liquid phase, at from 180 to 360.degree.C and under superatmospheric pressure, in the presence of a catalyst, by a process in which an iron catalyst obtained by reduction of an iron oxide with hydrogen at 500.degree.C is used.

公开(公告)号：GB1144214A

公开(公告)日：1969-03-05

申请号：GB2892266

申请日：1966-06-28

Applicant: BASF AG

Inventor： PLATZ ROLF ,  NOHE HEINZ ,  FRANK GERHARD

IPC: C07C5/48 ,  C07C17/00

Abstract: 1,144,214. Chlorostyrenes and homologues thereof. BADISCHE ANILIN- & SODAFABRIK A.G. 28 June, 1966 [29 June, 1965], No. 28922/66. Heading C2C. [Also in Division C5] Chlorine nuclear-substituted C 2 -C 4 alkyl benzenes are dehydrogenated with O 2 at 400-700‹ C. in the presence of iodine and an inert heat carrier which has an internal surface area of 0À1 to 15 sq. m./g. and a mean pore size of 300-30,000 Š to give chlorostyrenes. In Example 8 1.ethyl-2,5-dichlorobenzene is converted to dichlorostyrene and in Example 9 1 - ethyl - 2,4,6 - triohlorobenzene is converted to trichlorostyrene.