PROCESS FOR THE PURIFICATION OF CAPROLACTAM

    公开(公告)号:DE3061061D1

    公开(公告)日:1982-12-16

    申请号:DE3061061

    申请日:1980-05-21

    Applicant: BASF AG

    Abstract: A process for purifying caprolactam, which has been obtained by a Beckmann rearrangement, by extracting crude caprolactam with solvents, distilling the extract in the presence of alkali, and isolating pure caprolactam, wherein, in a first stage, caprolactam is distilled from the alkaline distillation residue at a bottom temperature of 130 DEG -160 DEG C., and is recycled to the distillation stage, the residue thus obtained is distilled, in a second stage, at a bottom temperature of 140 DEG -180 DEG C., and the distillate is treated with strongly acidic agents in a third stage and is then recycled to the extraction stage.

    PROCESS FOR REGENERATING INACTIVE AND POISENED PLATINUM CATALYSTS

    公开(公告)号:DE3660147D1

    公开(公告)日:1988-06-01

    申请号:DE3660147

    申请日:1986-02-28

    Applicant: BASF AG

    Abstract: Noble metal catalyst, in particular platinum catalysts, which are applied on carriers and have become poisoned by metals as a result of being used for many years in the preparation of hydroxyl-ammonium salts by catalytic reduction of nitric oxide with hydrogen in an aqueous mineral acid are regenerated by a process in which the metallic impurities are dissolved using nitric acid or aqua regia, the solution is neutralized, the troublesome metals are precipitated from the neutralized solution by means of a selective precipitating reagent, and the purified platinum solution is reused for the preparation of the catalyst. Organic complexing agents which form insoluble or sparingly soluble complexes with the metallic impurities are preferably used as precipitating reagents.

    9.
    发明专利
    未知

    公开(公告)号:DE3507832A1

    公开(公告)日:1986-09-11

    申请号:DE3507832

    申请日:1985-03-06

    Applicant: BASF AG

    Abstract: Noble metal catalyst, in particular platinum catalysts, which are applied on carriers and have become poisoned by metals as a result of being used for many years in the preparation of hydroxyl-ammonium salts by catalytic reduction of nitric oxide with hydrogen in an aqueous mineral acid are regenerated by a process in which the metallic impurities are dissolved using nitric acid or aqua regia, the solution is neutralized, the troublesome metals are precipitated from the neutralized solution by means of a selective precipitating reagent, and the purified platinum solution is reused for the preparation of the catalyst. Organic complexing agents which form insoluble or sparingly soluble complexes with the metallic impurities are preferably used as precipitating reagents.

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