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    1.
    发明专利
    未知

    公开(公告)号：DE59303358D1

    公开(公告)日：1996-09-05

    申请号：DE59303358

    申请日：1993-10-14

    Applicant: BASF AG

    Inventor： MUELLEN KLAUS PROF DR ,  QUANTE HERIBERT

    IPC: C07D221/18 ,  C07D471/06 ,  C09B5/62 ,  C09B57/08

    Abstract: Quaterrylenes of the formula in which the two radicals R are hydrogen, substituted or unsubstituted C1-C20-alkyl, or substituted or unsubstituted phenyl, process(es) for their preparation, and their use as fluorescent dyes or pigments.

    Aromatic naphthalene and perylene condensn. prods. - can be converted into conductive derivs. by doping with oxidising or reducing substances or by anodic oxidn.
    2.
    发明专利
    Aromatic naphthalene and perylene condensn. prods. - can be converted into conductive derivs. by doping with oxidising or reducing substances or by anodic oxidn. 未知

    公开(公告)号：DE4024647A1

    公开(公告)日：1992-02-06

    申请号：DE4024647

    申请日：1990-08-03

    Applicant: BASF AG

    Inventor： NAARMANN HERBERT DR ,  KOCH KARL HEINZ ,  LUETTKE WOLFGANG PROF DR ,  MUELLEN KLAUS PROF DR

    IPC: C07C15/20

    Abstract: Aromatic condensn. prods. of formula (Ia) and (Ib) are new. In the formulae, the dotted lines indicate that the naphthalene or perylene units may be bonded together by single or double bonds; R1 and R2 = H, 1-12C alkyl, 3-8C cycloalkyl, phenyl or benzyl; m = 1-500 and n = 0-500. Derivs. of these rendered conductive by doping with oxidising or reducing substances or by anodic oxidn. at 0.05-100 mA/cm2 are also claimed. USE/ADVANTAGE - The polymers (Ia) and (Ib) are stable at very high temps. and are soluble in organic solvents. By doping with oxidising substances, e.g. AsF5, SbF5, Br, I, TiCl4, solns. or suspension of metal halides e.g. FeCl3, ZrCl4 and AlCl3 in nitromethane, F-contg. nitrogen oxide cpds. in nitromethane/methylene chloride, transition metal halides and reducing substances, etc.; and anodic oxidn. using an electrolyte soln. comprising a soln. or suspension of a conductive salt e.g. with an alkali(ne earth) metal cation and an (in)organic anion such as BF4, AsF6, SbF6, SbCl6, perchlorate, sulphate, bisulphate, sulphonate, benzenesulphonate or benzoate, electrically conductive derivs. are obtd. The aromatic condensn. prods. (Ia) and (Ib) are useful heat insulators, e.g. as support substances for heating elements. The doped derivs. with increased electrical conductivity are useful in the mfr. of electrodes.

    New poly:benzoid systems prodn. used as electrical conductor
    5.
    发明专利
    New poly:benzoid systems prodn. used as electrical conductor 未知

    公开(公告)号：DE4244509A1

    公开(公告)日：1994-07-07

    申请号：DE4244509

    申请日：1992-12-30

    Applicant: BASF AG

    Inventor： NAARMANN HERBERT DR ,  MUELLEN KLAUS PROF DR

    IPC: C08G61/02 ,  H01B1/12 ,  C08G61/00 ,  H01B1/06

    Abstract: New polybenzoid systems (I) are obtd. by thermal treatment of biphenylene cpds. of the formula R1-Z-R2 (IIA) or bisbenzocyclobuta(1,2-a:2',1'-d)benzene cpds. of the formula R3-Z'-R5 at 100-1000 deg.C and 10 power(-6) to 1000 bar. In formulae, Z = a gp. of formula (IIIA); Z' = a gp. of formula (IIIB); R1-5 = H, 3-12C alkyl or biphenyl; or R1-2 = -O-O-R6 or (CR7R8-Z-(C9R10)nH; and/or R3-5 = -O-O-R12 pr opt. substd. -(CR13R14-Z'-CR15R16-)n-H; R6-10 and R12-16 = 1-12C alkyl or phenyl; or R7-10 and R13-16 = CN, CONH2 or COOR11; or R6-10 = opt. substd. -Z-H and/or R12-16 = opt. substd. -Z'-H; R11 = 1-12C alkyl; and n = 1-20.

    New copolymers with naphthylene units and electroconductive polymers - obtd. by doping them, useful in opto-electronics esp. nonlinear optics, coating etc.
    7.
    发明专利
    New copolymers with naphthylene units and electroconductive polymers - obtd. by doping them, useful in opto-electronics esp. nonlinear optics, coating etc. 未知

    公开(公告)号：DE4037799A1

    公开(公告)日：1992-06-04

    申请号：DE4037799

    申请日：1990-11-28

    Applicant: BASF AG

    Inventor： NAARMANN HERBERT DR ,  MUELLEN KLAUS PROF DR ,  KOCH KARL HEINZ

    IPC: C08C19/44 ,  C08F8/00 ,  H01B1/12

    Abstract: New copolymers (I) with naphthylene units are of the formula (I) where a, b and n = 1-100000; X = H, 1-12C alkyl, 5-12C cycloalkyl, 6-18C aryl, pyrrolyl or thienyl; A and B = gps. obtd. by oligo- or polymerisation of 2-4C alkenes, 4-5C conjugated dienes, styrene, alpha-methyl-styrene, phenols di-substd. in the 2- and 6-positions by 1-4C alkyl or phenyl gps., ethylene oxide or propylene oxide or by reactng aromatic dihalogen cpds. with aromatic di-OH cpds. or their mxits. USE/ADVANTAGE - (I) are claimed for use in the prodn. of electroconductive polymers by doping (I). (I) are thermostable and soluble in organic solvents and are useful in optoelectronics, esp. nonlinear optics, coatings, lacquers, etc. Electroconductive doped (I) are useful, e.g. as electrodes, electromagnetic wave screening materials, sensors, heating systems, as fillers in combination with TiO2 or titanates and in paints. (Dwg.0/0)

    New polymers from tetra;methylene cyclo-octane and benzoquinone - form electrically conductive material with arsenic penta:fluoride and/or iodine etc.
    8.
    发明专利
    New polymers from tetra;methylene cyclo-octane and benzoquinone - form electrically conductive material with arsenic penta:fluoride and/or iodine etc. 未知

    公开(公告)号：DE3933901A1

    公开(公告)日：1990-04-19

    申请号：DE3933901

    申请日：1989-10-11

    Applicant: BASF AG

    Inventor： NAARMANN HERBERT DR ,  MUELLEN KLAUS PROF DR ,  WOHLFAHRT WERNER

    IPC: C08G61/02 ,  H01B1/12 ,  H01M4/60

    Abstract: Polymeric materials contg. structural units of formula (I) are new. In formula, n = 1-1000. (I) are prepd. by Diels-Alder condensn. of tetramethylene cyclooctane (II) with benzoquinone (III) to form a condensate which is then treated with FeCl3 to convert it back into a benzoquinone form, and opt. repeating the process with addn. of (II) or (III). USE/ADVANTAGE - The (I) are converted into electrically conductive materials by addn. with exclusion of moisture of an effective amt. of a cpd. chosen from AsF5, SbF5, an aromatic sulphonic acid- or nitro-cpd., an anhydrous fluorocarboxylic acid or an anhydrous mineral acid and/or iodine. The electrically conductive polycondensates are useful antistatic additives for polymers, for prodn. of solar cells, for conversion and fixing of radiation, for prodn. of electric and magnetic switches, and for prodn. of electrodes. Addn. of a strong Lewis acid to the polycondensate gives p-conductors.

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