PYRAZOLE COMPOUNDS FOR CONTROLLING INVERTEBRATE PESTS
    2.
    发明申请
    PYRAZOLE COMPOUNDS FOR CONTROLLING INVERTEBRATE PESTS 审中-公开
    用于控制反相胶束的吡咯化合物

    公开(公告)号:WO2010034738A3

    公开(公告)日:2010-10-07

    申请号:PCT/EP2009062318

    申请日:2009-09-23

    CPC classification number: A01N43/90 C07D471/04 C07D487/04 C07D498/04

    Abstract: The present invention relates to a method for controlling invertebrate pests which method comprises treating the pests, their food supply, their habitat or their breeding ground or a plant, seed, soil, area, material or environment in which the pests are growing or may grow, or the materials, plants, seeds, soils, surfaces or spaces to be protected from pest attack or infestation with a pesticidally effective amount of a pyrazole compound of formulae I or II or a salt or an N-oxide thereof, wherein A is a pyrazole radical of the formulae A1 or A2, wherein # denotes the binding; D is a 5- or 6-membered heterocyclic radical fused to the pyrazole moiety; Rp1, Rp2 and Rpx are H, halogen, CN, NO2, C1-C10-alkyl, C2-C10- alkenyl, C2-C10-alkynyl, etc.; n is 0 to 4; or two radicals Rpx bound to the same ring- member may form an oxo substituent, or two radicals Rpx bound to adjacent ring- members may form a 3- to 7-membered fused cyclic radical; B is N or CR4, wherein R4 is H, halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, etc.; X1 is S, O or NR1a, wherein R1a is H, C1-C10-alkyl, etc.; X2 is O2a, NR2bR2c or S(O)mR2d, wherein m is 0, 1 or 2; R2a is C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, etc.; R2b, R2c are H, C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, etc.; R2d is C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl, etc.; R1 is H, CN, C1-C10-alkyl, C1-C10-haloalkyl, C3-C10-cycloalkyl, etc.; R2, R3 and R5 are H, halogen, CN, NO2, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, etc.; to a method for protecting plant propagation material and/or the plants which grow therefrom, to plant propagation material comprising at least one compound of formulae I or II, to a method for treating or protecting an animal from infestation or infection by parasites, to novel pyrazole compounds of formulae I or Il and agricultural composition containing those compounds.

    Abstract translation: 本发明涉及一种控制无脊椎害虫的方法,该方法包括处理害虫,其食物供应,栖息地或其繁殖地,或害虫生长或可能生长的植物,种子,土壤,面积,物质或环境 ,或用农药有效量的式I或II的吡唑化合物或其盐或N-氧化物防止害虫侵袭或侵染的材料,植物,种子,土壤,表面或空间,其中A为 式A1或A2的吡唑基,其中#表示结合; D是与吡唑部分稠合的5或6元杂环基; Rp1,Rp2和Rpx是H,卤素,CN,NO2,C1-C10-烷基,C2-C10-烯基,C2-C10-炔基等; n为0〜4; 或者与相同环成员结合的两个基团R px可以形成氧代取代基,或者与相邻环 - 成员键合的两个基团R px可以形成3-至7-元稠合的环状基团; B是N或CR 4,其中R 4是H,卤素,CN,NO 2,C 1 -C 4烷基,C 1 -C 4卤代烷基,C 1 -C 4 - 烷氧基等; X1是S,O或NR1a,其中R1a是H,C1-C10-烷基等; X 2是O 2 a,NR 2 b R 2c或S(O)m R 2d,其中m是0,1或2; R 2a是C 1 -C 4烷基,C 1 -C 4卤代烷基,C 3 -C 6环烷基等; R2b,R2c为H,C1-C4-烷基,C1-C4卤代烷基,C3-C6-环烷基等; R2d是C1-C4-烷基,C1-C4卤代烷基,C3-C6-环烷基等; R1是H,CN,C1-C10-烷基,C1-C10-卤代烷基,C3-C10-环烷基等; R2,R3和R5是H,卤素,CN,NO2,C1-C4-烷基,C1-C4-卤代烷基,C1-C4-烷氧基等; 涉及一种用于保护植物繁殖材料和/或从其生长的植物的方法,将包含至少一种式I或II化合物的植物繁殖材料用于治疗或保护动物免受寄生虫感染或感染的方法,用于新颖的 式I或II的吡唑化合物和含有这些化合物的农业组合物。

    PYRIDINE COMPOUNDS FOR CONTROLLING INVERTEBRATE PESTS III
    4.
    发明申请
    PYRIDINE COMPOUNDS FOR CONTROLLING INVERTEBRATE PESTS III 审中-公开
    用于控制无节幼虫的吡啶化合物III

    公开(公告)号:WO2012034959A3

    公开(公告)日:2012-08-16

    申请号:PCT/EP2011065708

    申请日:2011-09-12

    CPC classification number: A01N43/40 A01N43/54 A01N43/58 A01N43/60 A01N25/00

    Abstract: The present invention relates to a method for controlling invertebrate pests, in particular arthropod pests and nematodes, by using pyridine compounds of formulae (I) or (II) and the salts thereof, the tautomers thereof, the N-oxides thereof and the salts of the tautomers or N-oxides thereof, where the radical A is of the formula (A), wherein # denotes the point of attachment to the remainder of formulae (I) or (II), and wherein A1 is N or C-RA1, A2 is N or C-RA2, A3 is N or C-RA3, A4 is N or C-RA4 and A5 is N or C-RA5, provided that one or two of the variables A1, A2, A3, A4 or A5 is N; RA1, RA5, if present, are H, halogen, CN, NO2, C1-C6-alkyl, C1-C6-haloalkyl and the like; RA2, RA4, if present, are H, halogen, CN, NO2, C1-C10-alkyl, C1-C10-haloalkyl and the like; RA3, if present, is H, halogen, CN, NO2, C1-C10-alkyl, C1-C10-haloalkyl and the like; R1 is H, CN, C1-C10- alkyl, C1-C10-haloalkyl and the like; R2 is H, halogen, methyl, C1-haloalkyl and the like; R3 is H, halogen, C1-C4-alkyl, C1-C3-haloalkyl and the like; X1 is S, O or NR1a, wherein R1a is H, C1-C10-alkyl and the like; X2 is OR2a, NR2bR2c or S(O)mR2d, wherein m is 0, 1 or 2, R2a is C1-C4-alkyl, C1-C4-haloalkyl and the like, R2b and R2c are H, C1-C4-alkyl, C1-C4- haloalkyl and the like, or R2b and R2c together with the nitrogen atom to which they are bound form a heterocycle, and R2d is C1-C4-alkyl, C1-C4-haloalkyl, C3-C6-cycloalkyl and the like. The present invention further relates to a method for protecting plant propagation material and/or the plants which grow therefrom, to plant propagation material, comprising at least one compound of formulae (I) or (II), their salts or N-oxides, and to an agricultural composition containing at least one compound of formulae (I) or (II), their salts or N-oxides.

    Abstract translation: 本发明涉及通过使用式(I)或(II)的吡啶化合物及其盐,其互变异构体,其N-氧化物和以下物质的盐来控制无脊椎害虫,特别是节肢动物害虫和线虫的方法: 其中基团A具有式(A)的互变异构体或N-氧化物,其中#表示与式(I)或(II)的其余部分的连接点,并且其中A1是N或C-RA1, 条件是变量A1,A2,A3,A4或A5中的一个或两个是N或C-RA2,A3是N或C-RA3,A4是N或C-RA4并且A5是N或C-RA5。 N; RA1,RA5(如果存在)为H,卤素,CN,NO2,C1-C6-烷基,C1-C6-卤代烷基等; 如果存在,RA 2,RA 4是H,卤素,CN,NO 2,C 1 -C 10烷基,C 1 -C 10卤代烷基等; 如果存在,RA3为H,卤素,CN,NO2,C1-C10-烷基,C1-C10-卤代烷基等; R 1是H,CN,C 1 -C 10烷基,C 1 -C 10卤代烷基等; R2是H,卤素,甲基,C1-卤代烷基等; R3是H,卤素,C1-C4-烷基,C1-C3-卤代烷基等; X1是S,O或NR1a,其中R1a是H,C1-C10-烷基等; X2是OR2a,NR2bR2c或S(O)mR2d,其中m是0,1或2,R2a是C1-C4-烷基,C1-C4-卤代烷基等,R2b和R2c是H,C1-C4-烷基, C1-C4-卤代烷基等,或者R2b和R2c与它们所连接的氮原子一起形成杂环,R2d为C1-C4-烷基,C1-C4-卤代烷基,C3-C6-环烷基等 。 本发明进一步涉及保护植物繁殖材料和/或从其生长的植物到植物繁殖材料的方法,所述植物繁殖材料包含至少一种式(I)或(II)的化合物,其盐或N-氧化物,和 涉及含有至少一种式(I)或(II)化合物,其盐或N-氧化物的农业组合物。

    SULFONAMIDE COMPOUNDS
    7.
    发明申请
    SULFONAMIDE COMPOUNDS 审中-公开
    磺酰胺化合物

    公开(公告)号:WO2009153285A2

    公开(公告)日:2009-12-23

    申请号:PCT/EP2009057531

    申请日:2009-06-17

    Abstract: The present invention relates to sulfonamide compounds of formula (I) wherein R1 is H, halogen, CN, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-alkylthio, C2-C6-alkenylthio, C2-C6-alkynylthio, C1-C6-haloalkyl or C1-C6-haloalkoxy; R2 and R3 are H, halogen, CN, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-alkylthio, C2-C6-alkenylthio, C2-C6-alkynylthio, C1-C6-haloalkyl or C1-C6-haloalkoxy; or R2 together with R3 form a fused 5 or 6-membered carbocycle or heterocycle; R4 is halogen, CN, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C6-alkoxy, C1-C6-alkylthio, C1-C6-alkylsulfinyl, C1-C6-alkylsulfonyl, C1-C6-haloalkyl, C1-C6-haloalkoxy, C1-C6-haloalkylthio, C1-C6-haloalkylsulfinyl or C1-C6-haloalksulfonyl; n is 0, 1, 2 or 3; R5 is phenyl or a 5- or 6-membered heterocycle; X is O or NRx, wherein Rx is H, C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-alkylcarbonyl or C1-C6-alkylcarbonyloxy; Y is N or C(Ry), wherein Ry is H, halogen, CN, C1-C6-alkyl,C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C3-7-cycloalkyl- C1-C4-alkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-alkylthio, C2-C6-alkenylthio, C2-C6-alkynylthio, C1-C6-haloalkyl and C1-C6-haloalkoxy; and Z is a chemical bond, O or N(Rz), wherein Rz is C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C7-cycloalkyl, C1-C6-alkoxy, C2-C6-alkenyloxy, C1-C6-alkylcarbonyl or C1-C6-alkylcarbonyloxy; as well as to the N-oxides and salts thereof. These compounds are useful for combating animal pests. The invention also relates to a process for the preparation of these compounds and to intermediate compounds used in said process. The invention further relates to a method for controlling animal pests by using the compounds of formula (I), the N-oxides or the salts thereof, to plant propagation material and to an agricultural and veterinary composition comprising said compounds, the N-oxides or the salts thereof.

    Abstract translation: 本发明涉及式(I)的磺酰胺化合物,其中R1是H,卤素,CN,C1-C6-烷基,C2-C6-烯基,C2-C6-炔基,C3-C7-环烷基,C3-C7-环烷基 C 1 -C 4 - 烷基,C 1 -C 6 - 烷氧基,C 2 -C 6 - 烯氧基,C 2 -C 6 - 炔氧基,C 1 -C 6 - 烷硫基,C 2 -C 6 - 烯硫基,C 2 -C 6 - 炔硫基,C 1 -C 6 - 卤代烷基或C 1 1 -C 6 - 卤代烷氧基; R2和R3是H,卤素,CN,C1-C6-烷基,C2-C6-烯基,C2-C6-炔基,C3-C7-环烷基,C3-C7-环烷基-C1-C4-烷基,C1-C6- 烷氧基,C 2 -C 6 - 烯氧基,C 2 -C 6 - 炔氧基,C 1 -C 6 - 烷硫基,C 2 -C 6 - 烯硫基,C 2 -C 6炔硫基,C 1 -C 6卤代烷基或C 1 -C 6卤代烷氧基; 或R 2与R 3一起形成稠合的5或6元碳环或杂环; R4是卤素,CN,C1-C6-烷基,C2-C6-烯基,C2-C6-炔基,C1-C6-烷氧基,C1-C6-烷硫基,C1-C6-烷基亚磺酰基,C1-C6-烷基磺酰基,C1- C 1 -C 6卤代烷基,C 1 -C 6卤代烷硫基,C 1 -C 6卤代烷基亚磺酰基或C 1 -C 6卤代磺酰基; n为0,1,2或3; R5是苯基或5-或6-元杂环; X是O或NR x,其中Rx是H,C 1 -C 6烷基,C 2 -C 6 - 烯基,C 2 -C 6 - 炔基,C 3 -C 7 - 环烷基,C 1 -C 6 - 烷氧基,C 2 -C 6 - 烯氧基,C 2 -C 6 - 炔基氧基,C 1 -C 6 - 烷基羰基或C 1 -C 6烷基羰基氧基; Y是N或C(Ry),其中R y是H,卤素,CN,C 1 -C 6烷基,C 2 -C 6 - 烯基,C 2 -C 6炔基,C 3 -C 7 - 环烷基,C 3-7 - C 1 -C 6烷基,C 1 -C 6 - 烷氧基,C 2 -C 6 - 烯氧基,C 2 -C 6 - 炔氧基,C 1 -C 6 - 烷硫基,C 2 -C 6 - 烯硫基,C 2 -C 6 - 炔硫基, 卤代烷氧基; Z为化学键,O或N(Rz),其中Rz为C1-C6-烷基,C2-C6-烯基,C2-C6-炔基,C3-C7-环烷基,C1-C6-烷氧基,C2-C6 - 烯氧基,C1-C6-烷基羰基或C1-C6-烷基羰基氧基; 以及N-氧化物及其盐。 这些化合物可用于对抗动物害虫。 本发明还涉及制备这些化合物的方法和用于所述方法的中间体化合物。 本发明还涉及通过使用式(I)化合物,其N-氧化物或其盐来植物繁殖材料以及包含所述化合物,N-氧化物或其盐的农业和兽医组合物来控制动物害虫的方法 其盐。

    PESTICIDALLY ACTIVE COMPOSITIONS COMPRISING 3-ACETYL-1-PHENYLPYRAZOLE COMPOUNDS
    8.
    发明申请
    PESTICIDALLY ACTIVE COMPOSITIONS COMPRISING 3-ACETYL-1-PHENYLPYRAZOLE COMPOUNDS 审中-公开
    包含3-乙酰基-1-苯基甲基吡唑化合物的农药活性组合物

    公开(公告)号:WO2008092851A2

    公开(公告)日:2008-08-07

    申请号:PCT/EP2008051026

    申请日:2008-01-29

    Abstract: The present invention relates to pesticidal compositionscomprising as active componentsat least one 3-acetyl-1-phenylpyrazole compound of the formula (I) or a salt thereof: wherein X is N or C-R 5 ; R 1 is C 1 -C 4 -alkyl or C 1 -C 4 -haloalkyl; R 2 is NR 6 R 7 or S(O) n R 8 ; R 3 is halogen, C 1 -C 4 -haloalkyl, C 1 -C 4 -haloalkoxy, SF 5 or S(O) p R 9 ; R 4 is hydrogen or halogen; R 5 is halogen; R 6 is hydrogen, C 1 -C 4 -alkyl, C 1 -C 4 -haloalkyl,C(O)R 10 , S(O) q CF 3 ; R 7 is hydrogen or C 1 -C 4 -alkyl, or R 6 and R 7 are joined so as together form a C 4 - C 6 -alkylene moiety, wherein one CH 2 -group may be replaced by oxygen or a radical N-R 11 ; R 8 , R 9 , R 10 , R 11 are each independently hydrogen, C 1 -C 4 -alkylorC 1 -C 4 -haloalkyl; m, n, p and q are each independently 0, 1 or 2; and at least one further pesticidally active compound II, selected from A.1GABA-gated chloride channel antagonists; A.2Nicotinic acetylcholine receptor agonists/antagonists A.3Juvenile hormone mimics; A.4Compounds affecting the oxidative phosphorylation; A.5Inhibitors of the chitin biosynthesis; A.6Moulting disruptors; A.7Mitochondrial electron transport inhibitors;. A.8Voltage-dependent sodium channel blockers; A.9Inhibitors of the lipid synthesis; and A.10group of various compounds.

    Abstract translation: 本发明涉及具有式(I)的至少一种3-乙酰基-1-苯基吡唑化合物或其盐的活性成分的杀虫组合物:其中X是N或C-R 5; R 1是C 1 -C 4 - 烷基或C 1 -C 4 - (C 1 -C 4)烷基或C 1 -C 4 - > - 卤代烷基; R 2是NR 6 R 7或S(O)n R 8, ; R 3是卤素,C 1 -C 4 - 卤代烷基,C 1 -C 4烷基, / SO 2 - 烷基,SF 5或S(O)n R 9。 R 4是氢或卤素; R 5是卤素; R 6是氢,C 1 -C 4 - 烷基,C 1 -C 4 - C(O)R 10,S(O)q CF 3 3, R 7是氢或C 1 -C 4 - 烷基,或R 6和R 7 连接在一起形成C 4 -C 6亚烷基部分,其中一个CH 2 - 亚基可以被取代 通过氧或自由基NR 11; R 9,R 9,R 10,R 11,各自独立地为氢,C 1〜 / SUB> -C 4 -alkylorC 1 -C 4 - 卤代烷基; m,n,p和q各自独立地为0,1或2; 和至少一种另外的选自A.1GABA门控氯化物通道拮抗剂的杀虫活性化合物II; A.2烟碱乙酰胆碱受体激动剂/拮抗剂A.3避孕激素模拟物; A.4影响氧化磷酸化的化合物; A.5壳多糖生物合成抑制剂 A.6造成破坏者 A.7线粒体电子传递抑制剂 A.8电压依赖性钠通道阻滞剂; A.9脂质合成抑制剂; 和A.10组各种化合物。

    PYRAZOLE COMPOUNDS FOR CONTROLLING INVERTEBRATE PESTS
    9.
    发明申请
    PYRAZOLE COMPOUNDS FOR CONTROLLING INVERTEBRATE PESTS 审中-公开
    用于控制反相胶束的吡咯化合物

    公开(公告)号:WO2012076704A3

    公开(公告)日:2012-08-02

    申请号:PCT/EP2011072363

    申请日:2011-12-09

    Abstract: The present invention relates to a method for controlling invertebrate pests, in particular arthropod pests and nematodes, by using pyrazole compounds of formula (I) and the salts thereof, the tautomers thereof, the N-oxides thereof and the salts of the tautomers or N-oxides thereof, (I) wherein X is N or CH, Y is N or CH, Z is N or CH, provided that either only one of X, Y and Z is N or only two adjacent groups of X, Y and Z are N; and wherein Q is a bivalent 5- or 6-membered carbocyclic radical or a 5- or 6-membered heterocyclic radical having one heteroatom moiety which is selected from the group consisting of O, S, N or N-RQN as ring member and 0, 1 or 2 further heteroatom moieties N as ring members, wherein 0, 1, 2 or 3 of the ring members that are carbon atoms may carry a radical RQ, provided that the pyrazole radical and the 6-membered heteroaromatic radical are bound in ortho- or meta-position of Q with respect to each other, if Q is a 6-membered radical; and wherein RA, if present, is C1-C3-alkyl, C1-C3-haloalkyl or the like; n is 0, 1 or 2; RN is C1-C3-alkyl, C1-C2-haloalkyl, C1-C2-alkoxy-C1-C2-alkyl or the like; Rt and Ru are independently of each other selected from hydrogen, methyl and the like; RQN is hydrogen, C1-C4-alkyl or the like; RQ is hydrogen, halogen, C1-C4-alkyl or the like. The present invention further relates to a method for protecting plant propagation material and/or the plants which grow therefrom, to plant propagation material, comprising at least one compound of formula (I), their salts or N-oxides, and to pyrazole compounds of formula (I).

    Abstract translation: 本发明涉及通过使用式(I)的吡唑化合物及其盐,其互变异构体,其N-氧化物和互变异构体或N的盐来控制无脊椎害虫,特别是节肢动物害虫和线虫的方法 (I)其中X是N或CH,Y是N或CH,Z是N或CH,条件是X,Y和Z中只有一个是N或只有X,Y和Z的两个相邻基团 是N; 并且其中Q是二价5-或6-元碳环基团或具有一个杂原子部分的5-或6-元杂环基团,其选自O,S,N或N-RQN作为环成员,0 ,1个或2个另外的杂原子部分N作为环成员,其中作为碳原子的环成员的0,1,2或3可以携带自由基RQ,条件是吡唑基和6元杂芳族基团以邻位 - 或相对于Q的间位,如果Q是6元基团; 并且其中RA如果存在,是C 1 -C 3 - 烷基,C 1 -C 3 - 卤代烷基等; n为0,1或2; RN是C 1 -C 3烷基,C 1 -C 2卤代烷基,C 1 -C 2烷氧基-C 1 -C 2烷基等; Rt和Ru彼此独立地选自氢,甲基等; RQN是氢,C1-C4烷基等; RQ是氢,卤素,C1-C4烷基等。 本发明还涉及一种用于保护植物繁殖材料和/或从其生长的植物的方法,包括至少一种式(I)化合物,其盐或N-氧化物的植物繁殖材料,以及吡唑化合物 式(I)。

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