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公开(公告)号:US20230150938A1
公开(公告)日:2023-05-18
申请号:US17915116
申请日:2021-03-22
Applicant: BASF SE
Inventor: Rainer KLOPSCH , Peter OECHSLE , Harald WINSEL , Alexander Michael HAYDL , Joaquim Henrique TELES , Johann-Peter MELDER , Jan-Dirk ARNDT , Olaf KRIHA , Alexandre GUTHERTZ
IPC: C07D211/58 , H01M8/18 , H01M8/08
CPC classification number: C07D211/58 , H01M8/188 , H01M8/08 , H01M2300/0005
Abstract: The present invention relates to a solution comprising water and different 2,2,6,6-tetramethyl-piperidinyl-oxyl (TEMPO)-derivatives, a process for the production of this solution, a process for making a redox-flow cell comprising the solution as electrolyte, the redox-flow cell comprising the solution as an electrolyte in one chamber of the cell and the use of the redox-flow cell for storing electrical energy.
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公开(公告)号:US20200299255A1
公开(公告)日:2020-09-24
申请号:US16633870
申请日:2018-08-07
Applicant: BASF SE
Inventor: Peter RUDOLF , Jan-Dirk ARNDT , Nicole HOLUB , Verena MORMUL , Indre THIEL
IPC: C07D327/04 , C07C323/12 , B01J21/06 , C07C69/96
Abstract: Process for the preparation of a compound with at least one monothiocarbonate group by reacting:—a compound with at least one mercaptoalcohol group and—a dialkylcarbonate, in the presence of a catalyst wherein the catalyst is a salt of a metal selected from group IIIb or IVb of the periodic system.
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公开(公告)号:US20200010395A1
公开(公告)日:2020-01-09
申请号:US16460402
申请日:2019-07-02
Applicant: BASF SE
Inventor: Dagmar Pascale KUNSMANN-KEITEL , Georg Heinrich GROSCH , Jan-Dirk ARNDT , Gauthier Luc Maruice AVERLANT , Wolf-Steffen WEISSKER , Marcus Georg SCHREMS , Dan-Tam Daniel TANG
Abstract: Method for preparing a β-hydroxyketone having 4 to 8 carbon atoms by reacting formaldehyde with a branched or unbranched dialkyl ketone having 3 to 7 carbon atoms in the liquid phase in a reactor in the presence of a basic component at a temperature of 50 to 150° C. and a pressure of 0.2 to 10 MPa abs, in which (a) a trialkylamine having 1 to 4 carbon atoms per alkyl group is used as basic component and the reaction (b) is carried out in the presence of 1 to 25% by weight water, based on the liquid phase, and (c) at a molar ratio of trialkylamine to formaldehyde in the liquid phase of from 1 to 5.
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公开(公告)号:US20230150939A1
公开(公告)日:2023-05-18
申请号:US17915117
申请日:2021-03-22
Applicant: BASF SE
Inventor: Alexander Michael HAYDL , Peter OECHSLE , Harald WINSEL , Jan-Dirk ARNDT , Joaquim Henrique TELES , Johann-Peter MELDER , Olaf KRIHA , Rainer KLOPSCH
IPC: C07D211/58 , H01M8/18
CPC classification number: C07D211/58 , H01M8/188
Abstract: The present invention relates to a solution comprising water and different 2,2,6,6-tetramethyl-piperidinyl-oxyl (TEMPO)-derivatives, a process for the production of this solution, a process for making a redox-flow cell comprising the solution as electrolyte, a redox-flow cell comprising the solution as an electrolyte in one chamber of the cell and the use of the redox-flow cell for storing electrical energy.
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公开(公告)号:US20160096814A1
公开(公告)日:2016-04-07
申请号:US14889541
申请日:2014-05-15
Applicant: BASF SE
Inventor: Marcus G. Schrems , Jan EGGERT , Jan U MÜLLER , Jan-Dirk ARNDT , Günter GOTTWALD , Volker HÜTT
IPC: C07D309/18 , B01J31/02
CPC classification number: C07D309/18 , B01J31/0225
Abstract: The present invention relates to a method for producing dehydro rose oxide by reacting isoprenol and prenal in the presence of at least one sulfonic acid of formula R1—SO3H as catalyst, wherein R1 is selected from phenyl which carries 2 or 3 C1-C4-alkyl substituents, phenyl which carries one C8-C20-alkyl substituent and optionally also 1 or 2 C1-C4-alkyl substituents, and naphthyl which optionally carries 1 or 2 C1-C4-alkyl substituents.
Abstract translation: 本发明涉及通过在至少一种式R 1 -SO 3 H的磺酸作为催化剂的存在下使异戊二烯醇和衍生物反应来制备脱氢玫瑰氧化物的方法,其中R 1选自携带2或3个C 1 -C 4烷基 取代基,带有一个C 8 -C 20烷基取代基的苯基和任选地还有1或2个C 1 -C 4烷基取代基的苯基,和任选地带有1或2个C 1 -C 4烷基取代基的萘基。
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公开(公告)号:US20200369641A1
公开(公告)日:2020-11-26
申请号:US16634230
申请日:2018-08-07
Applicant: BASF SE
Inventor: Peter RUDOLF , Indre THIEL , Markus JEGELKA , Jan-Dirk ARNDT , Joaquim Henrique TELES
IPC: C07D327/04 , C07D411/12
Abstract: Process for the preparation of a compound with at least one five-membered cyclic monothiocarbonate group wherein a) a compound with at least one epoxy group is used as starting material b) the compound is reacted with phosgene or an alkyl chloroformate thus giving an adduct and c) the adduct is reacted with a compound comprising anionic sulfurthus obtaining the comound with at least one five-membered cyclic monothiocarbonate group.
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公开(公告)号:US20200010394A1
公开(公告)日:2020-01-09
申请号:US16460327
申请日:2019-07-02
Applicant: BASF SE
Inventor: Dagmar Pascale KUNSMANN-KEITEL , Georg Heinrich GROSCH , Jan-Dirk ARNDT , Gauthier Luc Maruice AVERLANT , Wolf-Steffen WEISSKER , Marcus Georg SCHREMS , Dan-Tam Daniel TANG
Abstract: Method for preparing 1-hydroxy-2-methyl-3-pentanone (I) by reacting formaldehyde with diethyl ketone in a reactor in the presence of water and a basic component at a temperature of 50 to 150° C. and a pressure of 0.2 to 10 MPa abs, in which the basic component used is a trialkylamine from the group comprising trimethylamine, N,N-dimethylethylamine, N,N-diethylmethylamine, triethylamine, N,N-dimethyl-n-propylamine, N-ethyl-N-methyl-n-propylamine, N,N-dimethylisopropylamine, N-ethyl-N-methylisopropylamine, N,N-dimethyl-n-butylamine, N,N-dimethylisobutylamine and N,N-dimethyl-sec-butylamine, and from the reaction mixture obtained, trialkylamine as low boiler and a bottom product comprising 1-hydroxy-2-methyl-3-pentanone (I) as high boiler are separated in a distillation apparatus, wherein the distillation apparatus is operated at a top pressure of 0.2 to 1 MPa abs.
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