公开(公告)号：US10202323B2

公开(公告)日：2019-02-12

申请号：US15744324

申请日：2016-07-15

Applicant: BASF SE

Inventor： Andrei-Nicolae Parvulescu ,  Ulrich Müller ,  Thomas Fenlon ,  Sumana Chaturvedula ,  Stefan Rüdenauer ,  Andreas Lanver ,  Ralf Pelzer ,  Klaus Ebel

IPC: C07C41/18 ,  B01J29/86 ,  B01J29/70

Abstract: A process for preparing an arylpropene from a diarylpropane by gas phase thermolysis in the presence of boron containing zeolitic material comprising a membered ring (MR) pore system greater than 10 MR.

公开(公告)号：US09695142B2

公开(公告)日：2017-07-04

申请号：US14787312

申请日：2014-04-28

Applicant: BASF SE

Inventor： Timon Stork ,  Karl Beck ,  Gabriele Gralla ,  Oliver Bey ,  Klaus Ebel

IPC: C07D321/00 ,  C07D315/00 ,  C07D309/10

CPC classification number: C07D309/10

Abstract: The present invention relates to a process for the preparation of 2-substituted 4-hydroxy-4-methyltetrahydropyrans.

公开(公告)号：US20160311741A1

公开(公告)日：2016-10-27

申请号：US15196320

申请日：2016-06-29

Applicant: BASF SE

Inventor： RUDOLF SCHUCH ,  Stefan Rüdenauer ,  Klaus Ebel ,  Ralf Pelzer ,  Andreas Keller

IPC: C07C29/44 ,  C11B9/00 ,  B01J37/18 ,  C07C29/80 ,  B01J23/46 ,  B01J37/02

CPC classification number: C07C29/44 ,  B01J21/08 ,  B01J23/462 ,  B01J23/56 ,  B01J33/00 ,  B01J35/0026 ,  B01J35/008 ,  B01J35/023 ,  B01J35/08 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/0203 ,  B01J37/18 ,  C07C29/19 ,  C07C29/80 ,  C07C2601/14 ,  C11B9/0061 ,  C07C33/20 ,  C07C31/1355

Abstract: A process for preparing 4-cyclohexyl-2-methyl-2-butanol, comprising: a) reaction of styrene with isopropanol at elevated temperature to obtain 2-methyl-4-phenyl-2-butanol, and b) heterogeneously catalyzed hydrogenation of 2-methyl-4-phenyl-2-butanol over a catalyst suitable for ring hydrogenation of aromatics, where the molar ratio of the styrene used in step a) to the isopropanol used in step a) is in the range from 1:below 5 to 1:0.5.

公开(公告)号：US08853471B2

公开(公告)日：2014-10-07

申请号：US14089114

申请日：2013-11-25

Applicant: BASF SE

Inventor： Stefan Rüdenauer ,  Klaus Ebel ,  Marta Porta Garcia

IPC: C07C27/00 ,  C07C45/00 ,  C07C29/44

CPC classification number: C07C29/44 ,  C07C45/002 ,  Y02P20/544 ,  C07C31/12 ,  C07C49/04

Abstract: Preparation of C4-oxygenates, in particular 2-butanol and butanone, which comprises the reaction of ethene with ethanol to form 2-butanol under conditions under which ethanol is present in the supercritical state.

Abstract translation: C4-含氧化合物，特别是2-丁醇和丁酮的制备，其包括在乙醇存在于超临界状态的条件下乙烯与乙醇的反应形成2-丁醇。

公开(公告)号：US09765001B2

公开(公告)日：2017-09-19

申请号：US15111841

申请日：2015-01-16

Applicant: BASF SE (Herzog Fiesser & Partner)

Inventor： Stefan Rüdenauer ,  Andreas Lanver ,  Ralf Pelzer ,  Klaus Ebel ,  Thomas Fenlon

IPC: C07C41/18

CPC classification number: C07C41/18 ,  C07C43/215

Abstract: The present invention relates to a process for preparing arylpropenes, especially 1-methoxy-4-(1-propenyl)benzene (anethole), by means of thermolysis of the corresponding 1,1-diarylpropanes.

公开(公告)号：US09717664B2

公开(公告)日：2017-08-01

申请号：US15092289

申请日：2016-04-06

Applicant: BASF SE

Inventor： Stefan Rüdenauer ,  Ralf Pelzer ,  Klaus Ebel ,  Martin Bock

IPC: A61Q13/00 ,  A61Q19/00 ,  C11D3/50 ,  A61K8/34 ,  C07C29/14 ,  C07C29/44 ,  C07C29/36 ,  C07C33/20 ,  C07C31/135 ,  C11D3/20 ,  C07C29/19

CPC classification number: A61K8/34 ,  A61K2800/10 ,  A61Q13/00 ,  A61Q19/00 ,  C07C29/19 ,  C07C29/44 ,  C07C2601/14 ,  C11D3/2024 ,  C11D3/2065 ,  C11D3/50 ,  C07C33/20 ,  C07C31/1355

Abstract: The present invention relates to processes for the preparation of compounds of the formula (Ia) by reacting styrene with a secondary alkanol and the hydrogenation of the resulting phenyl-substituted tertiary alkanol. In addition, the invention relates to compounds of the formula (Ia) and to the use of such compounds as fragrances, and also to compositions which comprise compounds of the formulae (Ia) and (Ib).

公开(公告)号：US09688650B2

公开(公告)日：2017-06-27

申请号：US14787285

申请日：2014-04-28

Applicant: BASF SE

Inventor： Timon Stork ,  Karl Beck ,  Klaus Ebel ,  Oliver Bey ,  Gabriele Gralla

IPC: C07D321/00 ,  C07D315/00 ,  C07D309/10

CPC classification number: C07D309/10

Abstract: The invention relates to a method for producing 2-substituted 4-hydroxy-4-methyltetrahydropyrans.

公开(公告)号：US09340754B2

公开(公告)日：2016-05-17

申请号：US14090626

申请日：2013-11-26

Applicant: BASF SE

Inventor： Stefan Rüdenauer ,  Ralf Pelzer ,  Klaus Ebel ,  Martin Bock

IPC: C11D3/50 ,  A61K8/34 ,  C07C29/19 ,  C07C29/44 ,  C07C33/20 ,  C11D3/20 ,  A61Q19/00

CPC classification number: A61K8/34 ,  A61K2800/10 ,  A61Q13/00 ,  A61Q19/00 ,  C07C29/19 ,  C07C29/44 ,  C07C2601/14 ,  C11D3/2024 ,  C11D3/2065 ,  C11D3/50 ,  C07C33/20 ,  C07C31/1355

Abstract: The present invention relates to processes for the preparation of compounds of the formula (Ia) by reacting styrene with a secondary alkanol and the hydrogenation of the resulting phenyl-substituted tertiary alkanol. In addition, the invention relates to compounds of the formula (Ia) and to the use of such compounds as fragrances, and also to compositions which comprise compounds of the formulae (Ia) and (Ib).

Abstract translation: 本发明涉及通过苯乙烯与仲链烷醇的反应和所得苯基取代的叔链烷醇的氢化制备式（Ia）化合物的方法。 此外，本发明涉及式（Ia）化合物和这些化合物作为香料的用途，还涉及包含式（Ia）和（Ib）的化合物的组合物。

公开(公告)号：US09139549B2

公开(公告)日：2015-09-22

申请号：US14053020

申请日：2013-10-14

Applicant: BASF SE

Inventor： Timon Stork ,  Oskar Röder ,  Klaus Ebel ,  Ralf Pelzer ,  Wolfgang Krause ,  Karl Beck

IPC: C07D309/04 ,  C07D309/10

CPC classification number: C07D309/10 ,  C07D309/04

Abstract: The present invention relates to a process for the integrated preparation of 2-substituted 4-hydroxy-4-methyltetrahydropyrans and of 2-substituted 4-methyltetrahydropyrans.

Abstract translation: 本发明涉及2-取代的4-羟基-4-甲基四氢吡喃和2-取代的4-甲基四氢吡喃的一体化制备方法。

公开(公告)号：US09073826B2

公开(公告)日：2015-07-07

申请号：US13687156

申请日：2012-11-28

Applicant: BASF SE

Inventor： Klaus Ebel ,  Tobias Voitl ,  Andreas Keller ,  Stefan Rüdenauer ,  Karsten Bartling ,  Bjorn Langlotz ,  Jochen Steiner

IPC: C07C303/22 ,  C07C309/15 ,  C07C303/32 ,  C07C303/44

CPC classification number: C07C303/22 ,  C07C303/32 ,  C07C303/44 ,  C07C309/15

Abstract: A process for preparing salts of acrylamido-2-methylpropanesulfonic acid (A) using the steps of: preparing a solution of a contaminated salt of acrylamido-2-methyl-propanesulfonic acid (A) in an anhydrous organic solvent (L) using at least one basic component (B) selected from the group of alkali metal oxides, alkaline earth metal oxides, alkali metal hydroxides, alkaline earth metal hydroxides and amines of the formula (I) NRaRbRc  (I) where the Ra, Rb and Rc radicals are each independently: hydrogen, C1-C4-alkyl, hydroxy-C1-C4-alkyl or C1-C4-alkoxy, where the molar ratio of compound (A) to the basic component (B) is 1:1 to 1:3, recovering the dissolved salt of compound (A) by crystallization or by precipitation, by altering the temperature and/or the pressure and/or the concentration of the salt in the solution. This leads to salts which are low in by-products and are particularly suitable for polymerization.

Abstract translation: 一种使用以下步骤制备丙烯酰氨基-2-甲基丙磺酸（A）的盐的方法：使用至少在无水有机溶剂（L）中制备丙烯酰胺基-2-甲基 - 丙磺酸（A）的污染盐的溶液 选自碱金属氧化物，碱土金属氧化物，碱金属氢氧化物，碱土金属氢氧化物和式（I）NRaRbRc（I）的胺的一种碱性组分（B），其中R a，R b和R c基团各自为 独立地：氢，C1-C4-烷基，羟基-C1-C4-烷基或C1-C4-烷氧基，其中化合物（A）与碱性组分（B）的摩尔比为1:1至1:3，回收 化合物（A）的溶解盐通过结晶或沉淀，改变溶液中盐的温度和/或压力和/或浓度。 这导致副产物低的盐，特别适用于聚合。