Abstract:
The invention relates to a method for producing aliphatic aldehydes of the general formula (I) by reacting aldehyde of the general formula (II) with an aldehyde of the general formula (III), where R1 is hydrogen or a methyl group, R2 is a straight-chain or branched alkyl radical having 1 to 4 carbon atoms, and the two X are each hydrogen or together are a further C-C bond, in the presence of an aldol condensation catalyst to form the substituted octenal of the general formula (I) and subsequently optionally hydration, either continuously or in batches, to form the corresponding octanal of the formula (I). The invention is characterized in that the aldehydes of the general formula III and II are used in a molar ratio of III:II between 1.4:1 and 0.6:1.
Abstract:
The invention relates to a method for producing gamma-hydroxycarboxylic esters and gamma-lactones, which are suitable as aromatic substances, by electrochemical reductive cross-coupling of alpha,beta-unsaturated esters with carbonyl compounds in an undivided electrolytic cell, said cell having a cathode that consists of lead, lead alloys, cadmium, cadmium alloys, mercury, steel, glassy carbon or boron-doped diamonds, and using an alkaline aqueous electrolyte comprising a conducting salt which suppresses cathodic hydrogen formation.
Abstract:
The present invention relates to a process for the preparation of 4-cyclohexyl-2-methyl-2-butanol. The process involves the following steps: a) reaction of styrene with isopropanol at elevated temperature, giving 4-phenyl-2-methyl-2-butanol, and b) heterogeneous-catalytic hydrogenation of 4-phenyl-2-methyl-2-butanol over a catalyst suitable for the ring hydrogenation of aromatics.
Abstract:
The invention relates to a method for producing m-substituted phenylalkanols of the formula (I), R1 denoting C1-C5-alkyl, and R2, R3, R4, and R5 independently denoting hydrogen or methyl, characterized in that a p-substituted phenylalkanol of the formula (II), where R1, R2, R3, R4, and R5 have the meanings given under formula (I), is isomerized in the presence of a Friedel-Craft catalyst to form an m-substituted phenylalkanol of the formula (I). The corresponding aldehydes known as fragrances and aroma chemicals can be formed as valuable products from the m-substituted phenylalkanols of the formula (I) by means of oxidation or dehydration.
Abstract:
The invention relates to a method for producing arylpropenes, in particular 1-methoxy-4-(1-propenyl)-benzene (anethole)1, by thermolysis of the corresponding 1,1-diarylpropanes.
Abstract:
The invention relates to a method for producing gamma-hydroxycarboxylic esters and gamma-lactones, which are suitable as aromatic substances, by electrochemical reductive cross-coupling of alpha,beta-unsaturated esters with carbonyl compounds in an undivided electrolytic cell, said cell having a cathode that consists of lead, lead alloys, cadmium, cadmium alloys, mercury, steel, glassy carbon or boron-doped diamonds, and using an alkaline aqueous electrolyte comprising a conducting salt which suppresses cathodic hydrogen formation.
Abstract:
The present invention relates to ethers of 1,2-, 1,3-and 1,4-bis(hydroxymethyl)cyclohexanes, to the preparation of such ethers and also to the use of such ethers as fragrances and as formulation auxiliaries in fragrance-comprising preparations.
Abstract:
Formulaciones hidrosolubles sólidas ópticamente transparentes de sustancias odoríferas y agentes aromatizantes, que contienen al menos una sustancia odorífera y un agente aromatizante sintéticos; en tales formulaciones, las sustancias odoríferas y los agentes aromatizantes se incorporan de manera homogénea en una matriz polimérica a base de polivinillactamas.
Abstract:
La invención se refiere a formulaciones de agente perfumante y aromatizante para aplicaciones tópicas, dichas formulaciones contienen como formador de matrices, una mezcla de al menos un polímero no hidrosoluble del grupo que contiene homopolímeros o copolímeros de ésteres de vinilo de ácido C1-C4-carboxílico y al menos un polímero hidrosoluble del grupo que contiene homopolímeros o copolímeros de N-viniIIactamas.
Abstract:
La presente invención se refiere al uso de cis- o trans-(2-isobutil-4-metiltetrahidropiran-4-il)acetato isoméricamente puro o altamente enriquecido con isómeros como productos químicos aromáticos. La invención además se refiere a un método para producir cis- o trans-(2- isobutil-4-metiltetrahidropiran-4-il)acetato isoméricamente puro o altamente enriquecido con isómeros y a los productos que se pueden obtener mediante este proceso. La invención además se refiere a una fragancia o composición de sustancia aromática que comprende cis- o trans-(2-isobutil-4-metiltetrahidropiran-4-il)acetato isoméricamente puro o altamente enriquecido con isómeros, a un método para impartir y/o intensificar un olor o sabor de un producto y también a productos aromatizados o saborizados que contienen cis- o trans-(2-isobutil-4-metiltetrahidropiran-4-il)acetato isoméricamente puro o altamente enriquecido con isómeros.