公开(公告)号：US09346035B2

公开(公告)日：2016-05-24

申请号：US14418487

申请日：2013-07-31

Applicant: BASF SE

Inventor： Sabine Huber ,  Tobias Rosendahl ,  Georg Seeber ,  Christian Baltes

IPC: C07C45/00 ,  B01J23/00 ,  B01J37/00 ,  B01J23/50 ,  B01J37/02 ,  B01J37/08 ,  B01J37/16 ,  B01J23/30 ,  B01J23/42 ,  B01J23/44 ,  B01J23/46 ,  B01J23/52 ,  B01J23/72 ,  C07C45/38 ,  B01J23/38 ,  C07C45/29 ,  C07C45/39 ,  B01J23/02 ,  B01J35/00

CPC classification number: B01J23/50 ,  B01J23/02 ,  B01J23/30 ,  B01J23/38 ,  B01J23/42 ,  B01J23/44 ,  B01J23/462 ,  B01J23/466 ,  B01J23/52 ,  B01J23/72 ,  B01J35/0006 ,  B01J37/02 ,  B01J37/0217 ,  B01J37/0219 ,  B01J37/0228 ,  B01J37/08 ,  B01J37/088 ,  B01J37/16 ,  C07C45/00 ,  C07C45/002 ,  C07C45/29 ,  C07C45/38 ,  C07C45/39 ,  C07C47/21

Abstract: Supported noble metal-comprising catalysts which can be obtained by a1) application of a noble metal compound, optionally in admixture with additives acting as promoters, to a support material, then drying, and a2) application of a reducing agent to a support material, then drying, wherein steps a1) and a2) are repeated simultaneously or in alternating turns, or wherein either of the compounds is applied entirely and then the other one is applied entirely, b) optionally afterwards drying of the resulting product, and c) subsequent calcination, its use, especially for oxidative dehydrogenation and a process for producing it.

Abstract translation: 负载型含贵金属的催化剂，其可以通过a1）将任选与作为助催化剂的添加剂混合的贵金属化合物施加到载体材料上，然后干燥，和a2）将还原剂施加到载体材料上， 然后干燥，其中步骤a1）和a2）同时或以交替匝重复，或者其中任何一种化合物全部施用，然后另一种化合物全部施用，b）任选地后续干燥所得产物，和c）随后 煅烧，其用途，特别是用于氧化脱氢及其制备方法。

公开(公告)号：US10562009B2

公开(公告)日：2020-02-18

申请号：US15765821

申请日：2016-10-04

Applicant: BASF SE

Inventor： Bernd Bastian Schaack ,  Helmut Wanisch ,  Barbara Wucher ,  Sabine Huber

IPC: B01J37/03 ,  B01J21/18 ,  B01J23/89 ,  B01J33/00 ,  C07C29/141 ,  B01J37/00 ,  B01J37/18 ,  C07C33/025

Abstract: The present invention relates to a process for producing iron-doped ruthenium-carbon support catalysts and also their use for the selective liquid-phase hydrogenation of carbonyl compounds to the corresponding alcohols, in particular for the hydrogenation of citral to geraniol or nerol or of citronellal to citronellal.

公开(公告)号：US20150151278A1

公开(公告)日：2015-06-04

申请号：US14418487

申请日：2013-07-31

Applicant: BASF SE

Inventor： Sabine Huber ,  Tobias Rosendahl ,  Georg Seeber ,  Christian Baltes

IPC: B01J23/50 ,  C07C45/00 ,  B01J37/02 ,  B01J37/08 ,  B01J23/02 ,  B01J35/00

CPC classification number: B01J23/50 ,  B01J23/02 ,  B01J23/30 ,  B01J23/38 ,  B01J23/42 ,  B01J23/44 ,  B01J23/462 ,  B01J23/466 ,  B01J23/52 ,  B01J23/72 ,  B01J35/0006 ,  B01J37/02 ,  B01J37/0217 ,  B01J37/0219 ,  B01J37/0228 ,  B01J37/08 ,  B01J37/088 ,  B01J37/16 ,  C07C45/00 ,  C07C45/002 ,  C07C45/29 ,  C07C45/38 ,  C07C45/39 ,  C07C47/21

Abstract: Supported noble metal-comprising catalysts which can be obtained by a1) application of a noble metal compound, optionally in admixture with additives acting as promoters, to a support material, then drying, and a2) application of a reducing agent to a support material, then drying, wherein steps a1) and a2) are repeated simultaneously or in alternating turns, or wherein either of the compounds is applied entirely and then the other one is applied entirely, b) optionally afterwards drying of the resulting product, and c) subsequent calcination, its use, especially for oxidative dehydrogenation and a process for producing it.

Abstract translation: 负载型含贵金属的催化剂，其可以通过a1）将任选与作为助催化剂的添加剂混合的贵金属化合物施加到载体材料上，然后干燥，和a2）将还原剂施加到载体材料上， 然后干燥，其中步骤a1）和a2）同时或以交替匝重复，或者其中任何一种化合物全部施用，然后另一种化合物全部施用，b）任选地后续干燥所得产物，和c）随后 煅烧，其用途，特别是用于氧化脱氢及其制备方法。

公开(公告)号：US12280365B2

公开(公告)日：2025-04-22

申请号：US17056753

申请日：2019-05-17

Applicant: BASF SE

Inventor： Marco Oskar Kennema ,  Christian Walsdorff ,  Fred Borninkhof ,  Matthias Johannes Wagner ,  Bernd Schube ,  Jochen Roerig ,  Gerald Bastian ,  Sabine Huber ,  Marcelo Daniel Kaufman Rechulski

IPC: B01J37/00 ,  B01J35/56 ,  B28B3/20 ,  B28B3/26 ,  B29C48/11 ,  B29C48/30 ,  B33Y10/00 ,  B33Y30/00 ,  B33Y70/00 ,  B33Y80/00

Abstract: The invention relates to a die (10) for the extrusion of catalyst molding, catalyst support molding, or adsorbent molding (60) in flow direction (32) of an extrudable composition from an entry side (12) to a discharge side (14) of the die comprising a shell (56) and comprising one or more channel-formers (18) which are displacers of the extrudable composition and which extend in flow direction of the extrudable composition, wherein the channel-formers (18) have been metal-printed.
It is preferable that this is free from cavities for receiving extrudable composition which extend at right angles to the flow direction (32) of the extrudable composition, and that this is free from connections running at right angles from channel-formers (18) to the interior side wall (22) of the die (10).
The invention further relates to a process for the production, by means of 3D metal printing, of a metal-printed die (10) for the extrusion of catalyst moldings/support moldings (60).

公开(公告)号：US11260371B2

公开(公告)日：2022-03-01

申请号：US16062242

申请日：2016-07-26

Applicant: BASF Corporation ,  BASF SE

Inventor： Feng Zhao ,  Jia Di Zhang ,  Liang Chen ,  Diana Carolina Galeano Nunez ,  Sabine Huber ,  Edgar Viktor Huennekes

IPC: B01J23/22 ,  B01D53/94 ,  B01J37/08 ,  B01J37/02 ,  B01D53/86 ,  B01J37/00 ,  B01J37/03 ,  B01J23/00 ,  B01J35/00 ,  B01J37/04 ,  B01J35/02 ,  B01J21/06

Abstract: A catalyst composition comprising—a support comprising TiO2,—a composite oxide containing vanadium and antimony, which has a rutile-type structure different from VSbO4 and V0.92Sb0.92O4 as determined by X-ray diffraction (XRD) analysis with CuKα radiation, and—optionally, one or more selected from the group consisting of oxides of silicon, oxides of vanadium and oxides of antimony, for selective catalytic reduction of nitrogen oxides; to a process for preparing the catalyst composition, to the catalyst composition obtained/obtainable by the process and to use of the same for selective catalytic reduction of nitrogen oxides.

公开(公告)号：US10414707B2

公开(公告)日：2019-09-17

申请号：US16084285

申请日：2017-03-14

Applicant: BASF SE

Inventor： Martine Dehn ,  Bernhard Brunner ,  Klaus Ebel ,  Sabine Huber

IPC: C07C29/56 ,  C07C45/38 ,  B01J23/00 ,  B01J21/04 ,  B01J21/08 ,  B01J23/44 ,  B01J23/52 ,  C07C33/03 ,  C07C47/21

Abstract: The present invention relates to a process for preparing 3-methyl-2-butenol (prenol) and 3-methyl-2-butenal (prenal) from 3-methyl-3-butenol (isoprenol), in which 3-methyl-3-butenol is subjected to a catalytic isomerization over a carbon-supported Pd catalyst in the presence of a gas mixture comprising 1% to 15% by volume of oxygen to obtain a first product mixture, and the first product mixture is subjected to an oxidative dehydrogenation over a Pd catalyst comprising SiO2 and/or Al2O3 as support material, or over a carbon-supported Pd/Au catalyst in the presence of a gas mixture comprising 5% to 25% by volume of oxygen.