METHOD FOR PRODUCING RANDOM RADICAL COPOLYMERS AND CORRESPONDING ACTIVE INGREDIENT COMPOSITIONS OBTAINABLE THEREFROM
    1.
    发明申请
    METHOD FOR PRODUCING RANDOM RADICAL COPOLYMERS AND CORRESPONDING ACTIVE INGREDIENT COMPOSITIONS OBTAINABLE THEREFROM 审中-公开
    用于生产统计自由基共聚物和那些可活性化合物

    公开(公告)号:WO2010063672A3

    公开(公告)日:2010-08-05

    申请号:PCT/EP2009066042

    申请日:2009-11-30

    Abstract: The invention relates to a method for producing random radical copolymers, characterized by the following steps: a) dissolving by heating a) at least one olefinically unsaturated sulfonic acid of formula (I); wherein n is 0 to 10; X represents O or NR5; R1 represents hydrogen or methyl; R2, R3 independently represent hydrogen or C1 to C6 alkyl and R5 represents hydrogen, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, aryloxyalkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)alkylaminoaryl, (di)arylaminoalkyl, alkylarylaminoalkyl or alkylarylaminoaryl, wherein the aryl groups can be mono- or polysubstituted, the salts thereof or mixtures of acid and salts and b) at least two structurally distinct olefinically unsaturated monomers of formula (II), wherein Y represents O or NR7; R5 represents hydrogen or methyl; R6 represents alkyl, hydroxyalkyl, (di)alkylaminoalkyl or (di)alkylaminoaryl and R7 represents hydrogen, alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, aryloxyalkyl, alkoxyaryl, hydroxyalkyl, (di)alkylaminoalkyl, (di)alkylaminoaryl, (di)arylaminoalkyl, alkylarylaminoalkyl or alkylarylaminoaryl, and c) optionally one or more olefinically unsaturated monomers which can be structurally distinct from components (a) and (b), and at least one initiator, either (i) in a solvent mixture which contains water and a solvent having a boiling point below 140°C and being soluble in water, or (ii) in one or more pure alcohols, and polymerizing said mixture in solution, the copolymer formed also remaining dissolved. The copolymers obtainable according to the above method are suitable as formulation adjuvants in agrochemical active ingredient compositions.

    Abstract translation: 一种用于无规自由基共聚物的制备方法的特征在于:a)式(I),其中n为0至10中的至少一个烯属不饱和磺酸; X是O或NR5; R1是氢或甲基; R2,R3独立地是氢或C1-C6烷基和R5是氢,烷基,芳基,烷基,芳基烷基,烷氧基烷基,芳氧基烷基,烷氧基芳基,羟烷基,(二)烷基氨基烷基,(二)烷基氨基芳基,(二)芳基氨基,Alkylarylaminoalkyl或alkylarylaminoaryl ,其中该芳基基团可以被取代一次或多次,平均它们的盐或酸和盐,和b)至少两种结构不同的式(II),其中Y是O或NR 7的烯属不饱和单体的混合物; R5是氢或甲基; R 6是烷基,羟烷基,(二)烷基氨基烷基或(二)烷基氨基芳基,并且R 7是氢,烷​​基,芳基,烷基,芳基烷基,烷氧基烷基,芳氧基烷基,烷氧基芳基,羟烷基,(二)烷基氨基烷基,(二)烷基氨基芳基,(二)芳基氨基,Alkylarylaminoalkyl 平均值或alkylarylaminoaryl,其中该芳基基团可以被取代一次或多次,和c)任选的一种或多种烯属不饱和单体,其在结构上是从组分(a)和(b)是不同的,d)至少一种引发剂无论是在(I) 溶剂混合物包含水和具有140℃以下的沸点的水溶性有机溶剂,溶解或(ii)在通过加热和聚合在溶液中,其中所形成的共聚物也溶解溶解一种或多种纯的醇。 通过该方法获得的共聚物适合作为农业化学活性成分组合物中的制剂助剂。

    POLYURETHANE THICKENER
    7.
    发明申请
    POLYURETHANE THICKENER 审中-公开
    聚氨酯增稠剂

    公开(公告)号:WO2012052383A3

    公开(公告)日:2013-07-11

    申请号:PCT/EP2011068072

    申请日:2011-10-17

    CPC classification number: C08G18/4833 C08G18/225 C08G2105/02

    Abstract: The present invention relates to a one-stage method for producing polyurethanes which contain at least three hydrophilic segments, at least four hydrophobic segments, optionally allophanate segments and/or isocyanurate segments and which are produced in the presence of alkaline earth metal carboxylates or zinc carboxylates. The present invention further relates to the thus obtained polyurethanes, to their use as thickener for aqueous preparations and to aqueous preparations containing such polyurethanes.

    Abstract translation: 本发明涉及用于制备聚氨酯,所述至少三个亲水性链段的一步骤的过程,至少四个疏水性片段,任选脲基甲酸酯和任选的异氰脲酸酯链段包含的段,在碱(土)金属或锌的羧酸盐的存在。 此外,本发明涉及本身以这种方式获得的聚氨酯,它们作为增稠剂的水性制剂,和含有这样的聚氨酯的含水制剂。

    POLYPEPTIDE AGENTS IN THE FORM OF CONJUGATES OF KERATIN-BINDING POLYPEPTIDES, POLYMERS, AND EFFECTOR MOLECULES, METHOD FOR THE PRODUCTION THEREOF, AND USE THEREOF
    10.
    发明申请
    POLYPEPTIDE AGENTS IN THE FORM OF CONJUGATES OF KERATIN-BINDING POLYPEPTIDES, POLYMERS, AND EFFECTOR MOLECULES, METHOD FOR THE PRODUCTION THEREOF, AND USE THEREOF 审中-公开
    多肽偶联物从角蛋白多肽,聚合物和执行方法的形式用于生产和使用

    公开(公告)号:WO2009112301A3

    公开(公告)日:2009-12-10

    申请号:PCT/EP2009050847

    申请日:2009-01-26

    Abstract: Disclosed are keratin-binding polypeptide agents in the form of conjugates (A'B'C') or (A'B'C'D') comprising (A') a polypeptide sequence derived from a keratin-binding polypeptide (A), and (B') a statistical average of at least one polymer chain derived from a water-soluble or water-dispersible polymer (B) that carries lateral and/or terminal reactive functional groups (b1) and is selected in such a way as to form a homogeneous aqueous solution or dispersion along with the keratin-forming polypeptide (A) to be reacted to form the conjugate (A'B'C') or (A'B'C'D') in standard conditions, the polypeptide (A) in said aqueous solution or dispersion still having a keratin-binding activity. (C') At least one linker group links the polymer chain (B') to the polypeptide sequence (A'), and (D') optionally, a statistical average of at least one effector group is linked to the polymer chain (B'). Also disclosed are a method for the production of said active polypeptide substances and the use thereof for modifying keratin and keratin-containing materials and producing cosmetic and pharmaceutical compositions.

    Abstract translation: 角蛋白多肽偶联物的形式(A'B'C“)或(A'B'C'D”),其包含(A“)从角蛋白结合多肽(A)衍生的多肽序列,(B”)在随机 指至少一个聚合物链,从水溶性或水分散性,侧链和/或末端反应性官能团(b1)的(B)带有聚合物衍生的,其是根据其与偶联物一起选择(A'B'C) 或(A'B'C'D“)要反应角蛋白的结合多肽的(a)在正常状态下,均匀的水溶液或分散体,其中所述多肽(a)中仍然有角蛋白的结合活性,所述(C”)的至少一个连接基团 具有多肽序列(A')的聚合物链(B')连接并且其中(D')任选地在统计平均值上与聚合物链(B')的至少一个效应子基团结合; 它们的制备方法及其用于改性含角蛋白和角蛋白的材料以及用于生产化妆品和药物组合物的用途。

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