公开(公告)号：WO1998019650A1

公开(公告)日：1998-05-14

申请号：PCT/US1997018966

申请日：1997-10-21

Applicant: DENTSPLY INTERNATIONAL INC.

Inventor： DENTSPLY INTERNATIONAL INC. ,  LU, Kewang ,  HAMMESFAHR, Paul, D.

IPC: A61K06/083

CPC classification number: A61K6/0835 ,  A61K6/0017 ,  A61K6/0023 ,  C08L33/00

Abstract: The invention provides dental composition system having curable liquid which is useful alone as a light curable composition and which is useful by mixing with a powder in preselected proportions to form dual cure compositions. The composition system is useful as bonding agent, cement, liner, base, restorative, pit and fissure sealants, and/or core build-up material, having improved adhesion to dentin. After storing the powder and the liquid in separate containers for at least two weeks and then mixing a portion of the powder and a portion of the liquid to form a mixture, the polymerizable compound polymerizes within 20 minutes of the mixing to form a first polymeric material having a flexural strength of at least 50 MPs, and an expansion in water at 37 DEG C after 90 days of less than 1 percent by volume.

Abstract translation: 本发明提供了具有可固化液体的牙科组合物体系，其可以单独用作光固化性组合物，并且可通过与预定比例的粉末混合来形成双重固化组合物而有用。 组合物系统可用作粘合剂，水泥，衬垫，基底，修复剂，凹坑和裂缝密封剂和/或芯堆积材料，具有改善的对牙本质的粘附性。 在将粉末和液体储存在分开的容器中至少两周后，然后将一部分粉末和一部分液体混合以形成混合物，可聚合化合物在混合后20分钟内聚合以形成第一聚合物材料 具有至少50MPs的弯曲强度，并且90天后在37℃下的水的膨胀小于1体积％。

公开(公告)号：WO1997027819A1

公开(公告)日：1997-08-07

申请号：PCT/US1997001737

申请日：1997-01-30

Applicant: DENTSPLY INTERNATIONAL INC.

Inventor： DENTSPLY INTERNATIONAL INC. ,  HUY-CAN, Dao ,  WARRIN, George, E. ,  FOULKES, Harvey, B. ,  PERDREAUX, Rene ,  LEE, Edward, W.

IPC: A61C17/20

CPC classification number: A61C17/20

Abstract: The invention provides a transducer activated subgingival tool for contacting subgingival tooth surfaces and directing a fluid adjacent to said surfaces, wherein the tool has an activated tip having a fluid inlet end, a subgingival outlet end, a step in the surface of the outer wall of said tip between said inlet end and said subgingival outlet end, and a fluid passageway wall internal to the tip. The passageway wall is formed in the inlet end generally along the longitudinal center axis of the inlet end of the tip.

Abstract translation: 本发明提供了一种用于接触龈下齿表面并引导邻近所述表面的流体的传感器激活的龈下工具，其中该工具具有活动的尖端，其具有流体入口端，龈下出口端，外壁表面中的台阶 所述入口端和所述龈下出口端之间的所述尖端以及所述尖端内部的流体通道壁。 通道壁通常沿着尖端入口端的纵向中心轴线形成在入口端。

公开(公告)号：WO1997002787A1

公开(公告)日：1997-01-30

申请号：PCT/US1996011597

申请日：1996-07-11

Applicant: DENTSPLY INTERNATIONAL INC.

Inventor： DENTSPLY INTERNATIONAL INC. ,  PETERSON, Kenneth, S. ,  JEFFERIES, Steven, R. ,  VIDRA, James, D.

IPC: A61C05/04

CPC classification number: A61K6/083 ,  A61C5/50

Abstract: A fluoride releasing dental pit and fissure sealant dispensing system including a cartridge having a nozzle with a capillary conduit wall enclosing a capillary passage extending to a dispensing opening from a cylindrical chamber enclosing a sustained release dental pit and fissure sealant composition having a viscosity of less than 30,000 cps and including a polymerizable acrylic monomer, fluoride releasing glass particles and a fluoride containing salt. The salt is at least one hundred percent more soluble in water than calcium fluoride. The nozzle has a length to diameter ratio of at least six, and is readily bendable to form an arc of at least 30 degrees between the center line of the cylindrical chamber and the center line of the distal end of the nozzle.

Abstract translation: 氟化物释放牙槽和裂缝密封剂分配系统，其包括具有喷嘴的药筒，所述药筒具有毛细管导管壁，所述毛细管导管壁包围毛细管通道，所述毛细管通道从包围持续释放牙槽的圆柱形腔和具有小于 30,000cps，包括可聚合的丙烯酸单体，氟化物释放玻璃颗粒和含氟化物的盐。 该盐比氟化钙更易溶于水百分之一百以上。 喷嘴的长径比至少为6，并且容易弯曲，以在圆柱形腔室的中心线与喷嘴的远端的中心线之间形成至少30度的弧度。

公开(公告)号：WO1998026748A2

公开(公告)日：1998-06-25

申请号：PCT/US1997023095

申请日：1997-12-11

Applicant: DENTSPLY INTERNATIONAL INC.

Inventor： DENTSPLY INTERNATIONAL INC. ,  FIEDLER, Jurgen, Hans

IPC: A61K06/00

CPC classification number: A61K6/10 ,  C08G77/12 ,  C08G77/18 ,  C08G77/20 ,  C08G77/44 ,  C08G77/70 ,  C08G77/80 ,  C08L83/04 ,  C08L83/00 ,  C08L2666/28 ,  C08L2666/54

Abstract: Improved two component polymerizable polyorganosiloxane compositions are described, particularly for use in making dental impressions, having improved tear strength and wettability. Improved tear strength results from inclusion of a quadri-functional polysiloxane having a vinyl content of 0.16 to 0.24 m-mole/g. Working time is maintained by including sufficient amounts of a retarder composition that delays onset of the vinyl polymerization. Wettability is improved by including a surfactant resulting in a surface contact angle with water at three minutes of less than 50 DEG . The surfactant chosen has an HLB of 8-11, such that the wetting contact angle is achieved within less than two minutes and remains wetting throughout the working time of the impression taking, substantially improving impression quality. A low viscosity impression material is provided and includes a base component and a catalyst component. Both components are siloxane-based materials.

Abstract translation: 描述了改进的双组分可聚合聚有机硅氧烷组合物，特别是用于制造牙印痕，具有改善的撕裂强度和润湿性。 通过包含乙烯基含量为0.16〜0.24m摩尔/ g的四官能聚硅氧烷，提高撕裂强度。 通过包括足够量的缓凝剂组合物延长乙烯基聚合的开始来维持工作时间。 通过在三分钟以下的表面活性剂中含有与水的表面接触角小于50℃，提高润湿性。 所选择的表面活性剂具有8-11的HLB，使得在不到两分钟内实现润湿接触角，并且在印模的整个工作时间内保持润湿，从而显着提高了印刷质量。 提供了低粘度压印材料，并且包括基础组分和催化剂组分。 两种组分都是硅氧烷类材料。

公开(公告)号：WO1997029732A1

公开(公告)日：1997-08-21

申请号：PCT/US1997002342

申请日：1997-02-13

Applicant: DENTSPLY INTERNATIONAL INC.

Inventor： DENTSPLY INTERNATIONAL INC. ,  HAMMESFAHR, Paul, D. ,  LU, Kewang ,  SILVER, Paul, A.

IPC: A61K06/083

CPC classification number: C07C69/92 ,  A61C5/64 ,  A61C5/66 ,  A61K6/0017 ,  A61K6/0023 ,  A61K6/083 ,  A61K6/0835 ,  C08L33/00 ,  C08L43/02

Abstract: The invention provides polymerizable dental, compounds, compositions, including the compounds and products for mixing the compositons and methods of using the compositions. Aryl acid compounds are provided in accordance with the invention. The compositions include at least one polymerizable aryl acid compound, an effective amount of a polymerization initiator, and at least 10 percent by weight of ceramic, metal and/or metal oxide filler particles having a particle size less than 500 microns. The dental products of the invention include a polymerizable composition in an enclosure having at least two chambers separated by a wall adapted to be ruptured prior to or during mixing of the composition. Compositions of the invention are preferred for use in these enclosures. Core build up material including a polymerizable acid containing compound is used to support dental crowns and adhere them to teeth in accordance with the invention.

Abstract translation: 本发明提供可聚合的牙科，化合物，组合物，包括用于混合组合物的化合物和产物以及使用组合物的方法。 根据本发明提供了芳酸化合物。 组合物包括至少一种可聚合芳基化合物，有效量的聚合引发剂和至少10重量％的具有小于500微米的粒度的陶瓷，金属和/或金属氧化物填料颗粒。 本发明的牙科产品包括在外壳中的可聚合组合物，其具有至少两个由适于在组合物混合之前或混合期间被破裂的壁隔开的腔室。 本发明的组合物优选用于这些外壳。 根据本发明，使用包含可聚合酸的化合物的核心堆积材料来支撑牙冠并将其粘附到牙齿上。

公开(公告)号：WO1998031742A1

公开(公告)日：1998-07-23

申请号：PCT/US1997023886

申请日：1997-12-31

Applicant: DENTSPLY INTERNATIONAL INC.

Inventor： DENTSPLY INTERNATIONAL INC. ,  WILNER, Ralf

IPC: C08L23/02

CPC classification number: B32B27/32 ,  B32B1/08 ,  B32B27/08 ,  B32B27/306 ,  B32B27/34 ,  B32B27/36 ,  B32B27/38 ,  B32B2323/04 ,  B32B2323/043 ,  B32B2331/04 ,  B32B2439/60 ,  C08J5/18 ,  C08J2323/02 ,  C08L23/02 ,  C08L23/08 ,  C08L51/06 ,  C08L101/00 ,  C08L2205/08 ,  C08L2666/24 ,  C08L2666/14 ,  C08L2666/04

Abstract: A laminar package material for packaging of volatile compositions containing solvents with a vapor pressure of from about 90 hPa to about 300 hPa at 20 DEG C, includes a combination of a polyolefin (A), a second polymer (B) serving as a barrier material incompatible with the polyolefin and an alkylcarboxyl-substituted polyolefin serving as a compatibilizer (C).

Abstract translation: 用于包装含有20℃蒸汽压为约90hPa至约300hPa的溶剂的挥发性组合物的层状包装材料包括聚烯烃（A），作为阻隔材料的第二聚合物（B） 与聚烯烃和用作增容剂的烷基羧基取代的聚烯烃（C）不相容。

公开(公告)号：WO1998012980A1

公开(公告)日：1998-04-02

申请号：PCT/US1997017589

申请日：1997-09-22

Applicant: DENTSPLY INTERNATIONAL INC.

Inventor： DENTSPLY INTERNATIONAL INC. ,  SCHUMAN, Robert, J. ,  GUILMETTE, V., Richard ,  SEPTIMUS, Martin, I. ,  CORBELLINI, Alfred, E.

IPC: A61C01/00

CPC classification number: A61C1/0084 ,  A61C3/025

Abstract: An ultrasonic dental tooth treatment system including an ultrasonic dental handpiece, a fluid reservoir housing and a power control housing. The reservoir housing is supported by the control housing. The reservoir housing encloses two containers which are connected to the selector valve. The selector valve is connected to a control housing conduit which is connected to the handpiece. The control housing encloses a power control circuit which is connected to the handpiece. In a preferred embodiment of the invention a fluid dispenser includes at least one readily removable reservoir container supported by a reservoir housing having a pivotable cover and a fluid control valve. The cover is pivotable between an open position and a closed position. The valve is closed by the cover when the cover is in its open position.

Abstract translation: 一种超声牙齿治疗系统，包括超声波牙齿手柄，流体储存器壳体和功率控制壳体。 储存器壳体由控制壳体支撑。 储存器壳体包围两个连接到选择阀的容器。 选择阀连接到连接到手持件的控制壳体导管。 控制壳体包围连接到手持件的功率控制电路。 在本发明的一个优选实施例中，流体分配器包括至少一个易于拆卸的容器容器，其由具有可枢转盖和流体控制阀的储存器壳体支撑。 盖可在打开位置和关闭位置之间枢转。 当盖子处于其打开位置时，阀门被盖子封闭。

公开(公告)号：WO1998011844A1

公开(公告)日：1998-03-26

申请号：PCT/US1997015304

申请日：1997-09-08

Applicant: DENTSPLY INTERNATIONAL INC.

Inventor： DENTSPLY INTERNATIONAL INC. ,  JOVANOVIC, Vidan ,  CORBELLINI, Alfred, E. ,  ROSE, Emery ,  WARRIN, George, E. ,  PASCHKE, Richard, H.

IPC: A61C17/20

CPC classification number: B06B1/0253 ,  A61C17/20 ,  B06B2201/58 ,  B06B2201/76

Abstract: The invention provides a method of operating a dental scalar system having a vibrating scaling tip by continuously monitoring the amplitude and frequency of vibration of the tip which provides scaling power to a tooth in a patient's mouth. The amplitude and frequency of vibration of the tip is continuously adjusted to maintain a substantially constant scaling power. Preferably, the insert is vibrated at its resonant frequency and the system provides a substantially constant tip motion while the user varies the applied pressure between the tip and the tooth.

Abstract translation: 本发明提供了一种通过连续地监测尖端的振动的振幅和频率来为患者的口中的牙齿提供缩放力的操作具有振动缩放尖端的牙科标量系统的方法。 连续地调节尖端的振幅和频率以保持基本恒定的定标功率。 优选地，插入件以其谐振频率振动，并且系统在用户改变尖端和牙齿之间施加的压力时提供基本上恒定的尖端运动。

公开(公告)号：WO1995025501A1

公开(公告)日：1995-09-28

申请号：PCT/US1995003737

申请日：1995-03-23

Applicant: DENTSPLY INTERNATIONAL INC.

Inventor： DENTSPLY INTERNATIONAL INC. ,  HARE, Robert, V. ,  HAMMESFAHR, Paul, D.

IPC: A61K07/20

CPC classification number: A61Q11/00 ,  A61K8/22 ,  A61K8/4993

Abstract: A composition useful for removing and cleaning an oral dentition of organic residues that interfere with dental material activity, such as inhibiting curing of silicone based impression material. The composition is useful for cleaning temporary adhesive from a dentition prior to permanently adhering a crown, onlay, inlay or the like thereto and removing contaminating glove residues or the like from a dentition prior to taking of an impression. A method of preparing an impression of a dentition in the oral cavity, for removing inhibitors left by latex gloves that interfere with platinum catalyzed hydrosilation reactions, includes applying the decontaminating composition including surfactants, especially a polyoxyethylene surfactant, hydrogen peroxide and water to the area that is to have its impression taken substantially immediately before applying the impression taking material. The composition is rinsed from the area and, after drying, the taking of the dental impression proceeds free of surface inhibition of curing.

Abstract translation: 用于去除和清洁干扰牙科材料活性的有机残留物的口腔齿列的组合物，例如抑制硅氧烷基印模材料的固化。 在将冠状物，镶嵌物，镶嵌物等永久性粘合之前，该组合物可用于从牙列清洁临时粘合剂，并在取出印象之前从牙列中除去污染的手套残留物等。 制备口腔中牙列印模的方法，用于除去干涉铂催化硅氢化反应的乳胶手套留下的抑制剂，包括将去污组合物，包括表面活性剂，特别是聚氧乙烯表面活性剂，过氧化氢和水应用于 是在施加印象材料之前立即给予其印象。 从该区域漂洗该组合物，并且在干燥之后，使得牙齿印模进行无表面抑制固化。

公开(公告)号：WO1998024831A1

公开(公告)日：1998-06-11

申请号：PCT/US1997021847

申请日：1997-12-01

Applicant: DENTSPLY INTERNATIONAL INC.

Inventor： DENTSPLY INTERNATIONAL INC. ,  KLEE, Joachim, E.

IPC: C08G83/00

CPC classification number: C08G83/003 ,  C08G65/22 ,  C08G65/26 ,  C08G2261/126 ,  C08G2650/34

Abstract: Epoxide-amine dendrimers synthesized by a repetitive and step-wise addition reaction of epoxides comprising functional moieties which are available for conversion into amino groups followed by a reaction of these groups to primary amino moieties. The amino terminated dendrimers are reacted with (2,3-epoxypropoxy) methacrylate, a monoepoxide and/or a monoisocyanate. The methacrylate terminated dendrimers are polymerizable using redox initiators and/or photoinitiators. The resulting dendrimers show a very low volume shrinkage from that of the starting materials, on the order of less than about 5 % by volume.

Abstract translation: 通过环氧化物的重复和逐步加成反应合成的环氧化物 - 胺树枝状聚合物，所述环氧化物包含可用于转化为氨基的官能部分，随后将这些基团与伯氨基部分反应。 氨基封端的树枝状大分子与（2,3-环氧丙氧基）甲基丙烯酸酯，单环氧化物和/或单异氰酸酯反应。 甲基丙烯酸酯封端的树枝状大分子使用氧化还原引发剂和/或光引发剂是可聚合的。 所得到的树枝状聚合物显示出与起始原料相当的体积收缩率非常小，约小于约5体积％。