Abstract:
A premium synthetic lubricant having antiwear properties comprises a synthetic isoparaffinic hydrocarbon base stock and an effective amount of at least one antiwear additive. The antiwear additive is preferably at least one of a metal phosphate, a metal dialkyldithiophosphate, a metal dithiophosphate, a metal thiocarbamate, a metal dithiocarbamate, an ethoxylated amine dialkyldithiophosphate and an ethoxylated amine dithiobenzoate. Metal dialkyldithiophosphates are preferred, particularly zincdialkyldithiophosphate (ZDDP). The base stock is derived from a waxy, Fischer-Tropsch synthesized hydrocarbon feed fraction comprising hydrocarbons having an initial boiling point in the range of about 650-750 DEG F, by a process which comprises hydroisomerizing the feed and dewaxing the isomerate. The lubricant may also contain hydrocarbonaceous and synthetic base stock material in admixture with the Fischer-Tropsch derived base stock.
Abstract:
A wide-cut lubricant base stock is made by hydroisomerizing and then catalytically dewaxing a waxy Fischer-Tropsch synthesized hydrocarbon fraction feed and comprises the entire dewaxate having an initial boiling point in the 650-750 DEG F+ range. Formulated lubricating oils made by admixing the base stock with a commercial automotive additive package meet all specifications, including low temperature properties, for multigrade internal combustion engine crankcase oils. The waxy feed has an initial boiling point in the 650-750 DEG F range and continuously boils to an end point of at least 1050 DEG F+. Lower boiling hydrocarbons produced by the process are separated from the base stock by simple flash distillation. The base stock comprises the entire dewaxate having an initial boiling point in the 650-750 DEG F range.
Abstract:
Premium synthetic lubricants comprise a synthetic isoparaffinic hydrocarbon base stock and an effective amount of at least one, and typically a plurality of lubricant additives such as a detergent, dispersant, antioxidant, antiwear additive, pout point depressant, VI improver and the like. The base stock is derived from a waxy, paraffinic, Fischer-Tropsch synthesized hydrocarbon feed fraction having an initial boiling point in the range of about 650-750 DEG F and continuously boiling up to at least 1050 DEG F, by a process which comprises hydroisomerizing the feed and dewaxing the isomerate. The waxy feed has a T90-T10 temperature difference of at least 350 DEG F and is preferably hydroisomerized without any pretreatment, other than optional fractionation. The lubricant may also contain hydrocarbonaceous and synthetic base stock material. Lubricants, such as fully formulated multigrade automotive crankcase and transmission oils formed by adding a suitable additive package to the isoparaffinic base stock have exhibited performance superior to similar fully formulated oils based on both PAO and conventional, petroleum derived base stocks.
Abstract:
A lubricant-fuel mixture containing an amine salt and/or amide of a benzoic acid or thiobenzoic acid derivative, an amine salt of a phosphoric acid derivative, or certain quaternary ammonium hydroxides is effective in reducing the smoke emitted during operation of a two-cycle internal combustion engine.
Abstract:
A premium synthetic lubricant having antiwear properties comprises a synthet ic isoparaffinic hydrocarbon base stock and an effective amount of at least one antiwear additive. The antiwear additive is preferably at least one of a met al phosphate, a metal dialkyldithiophosphate, a metal dithiophosphate, a metal thiocarbamate, a metal dithiocarbamate, an ethoxylated amine dialkyldithiophosphate and an ethoxylated amine dithiobenzoate. Metal dialkyldithiophosphates are preferred, particularly zincdialkyldithiophospha te (ZDDP). The base stock is derived from a waxy, Fischer-Tropsch synthesized hydrocarbon feed fraction comprising hydrocarbons having an initial boiling point in the range of about 650-750 ~F, by a process which comprises hydroisomerizing the feed and dewaxing the isomerate. The lubricant may also contain hydrocarbonaceous and synthetic base stock material in admixture wit h the Fischer-Tropsch derived base stock.
Abstract:
Premium synthetic lubricants comprise a synthetic isoparaffinic hydrocarbon base stock and an effective amount of at least one, and typically a plurality of lubricant additives such as a detergent, dispersant, antioxidant, antiwear additive, pout point depresant, VI improver and the like. The base stock is derived from a waxy, paraffinic, Fischer-Tropsch synthesized hydrocarbon feed fraction having an initial boiling point in the range of about 650-750° F. and continuously boiling up to at least 1050° F., by a process which comprises hydroisomerizing the feed and dewaxing the isomerate. The waxy feed has a T90-T10 temperature difference of at least 350° F. and is preferably hydroisomerized without any pretreatment, other than optional fractionation. The lubricant may also contain hydrocarbonaceous and synthetic base stock material. Lubricants, such as fully formulated multigrade automotive crankcase and transmission oils formed by adding a suitable additive package to the isoparaffinic base stock have exhibited performance superior to similar fully formulated oils based on both PAO and conventional, petroleum derived base stocks.
Abstract:
A lubricating composition having improved anti-wear properties comprises: A. a lubricating oil basestock; B. a metal phosphate; C. a metal carbamate; and D. an alkyl hydroxy-aryl sulfide. The metal phosphate is preferably a dialkylphosphate, zinc compounds being especially suitable. From about 0.1 to about 1.0 wt.% (based on the basestock) is preferred. The metal carbamate is preferably a dithiocarbamate, more especially zinc compounds. From about 0.1 to about 1.3 wt.% is preferred. The sulfide is preferably an alkyl phenol sulfide, for example, nonyl phenol sulfide. From about 0.2 to about 2 wt.% is preferred.
Abstract:
This invention involves the preparation of selected metal dithiobenzoates by electrolysis of a substituted dithiobenzoic acid with a metal. It further involves the use of such metal dithiobenzoates as additives in lubricating hydrocarbon compositions.
Abstract:
This invention involves the preparation of selected metal dithiobenzoates by electrolysis of a substituted dithiobenzoic acid with a metal. It further involves the use of such metal dithiobenzoates as additives in lubricating hydrocarbon compositions.